18027-61-7Relevant academic research and scientific papers
Ruthenium-catalyzed dealkenative N-silylation of amines by substituted vinylsilanes
Marciniec, Bogdan,Kostera, Sylwia,Wyrzykiewicz, Bozena,Pawlu, Piotr
supporting information, p. 782 - 786 (2015/02/19)
The ruthenium hydride complex-catalyzed N-silylation of primary and secondary amines with substituted vinylsilanes, with the general formula R1CHCHSiR′3 (where R1 = H, Ph, n-Bu, Si(OEt)3), leading to the formation of a Si-
Indirect Nuclear Spin-Spin Coupling Constants of Nitrogen-15 to Silicon-29 in Silylamines
Kupce, Eriks,Liepins, Edvards,Pudova, Olga,Lukevics, Edmunds
, p. 581 - 582 (2007/10/02)
The 15N-29Si spin-spin coupling constants in silylamines have been measured from 29Si satellites in their natural abundance 15N n.m.r. spectra in an INEPT sequence for accumulation of signals and interpreted in terms of Fermi-contact interaction; the sensitivity of 1J(15N-29Si) to d?-p? bonding was noted.
