180477-54-7

Basic information

• Product Name: Cyclohexane, 4-methyl-2-[(3-methyl-2-butenyl)oxy]-1-(1-methylethyl)-, (1S,2R,4R)-
• CAS NO: 180477-54-7
• Molecular Formula: C15H28O
• Molecular Weight: 224.387
• Mol File: 180477-54-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 4-methyl-2-[(3-methyl-2-butenyl)oxy]-1-(1-methylethyl)-, (1S,2R,4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 4-methyl-2-[(3-methyl-2-butenyl)oxy]-1-(1-methylethyl)-, (1S,2R,4R)-(180477-54-7)
• EPA Substance Registry System: Cyclohexane, 4-methyl-2-[(3-methyl-2-butenyl)oxy]-1-(1-methylethyl)-, (1S,2R,4R)-(180477-54-7)

Safety Data

• Hazardous Substances Data: 180477-54-7(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 870-63-3 prenyl bromide 
• 753488-83-4 (1S,2R,4R)-2-(2,3-dimethylbut-2-en-1-yloxy)-1-isopropyl-4-methylcyclohexane 
• 195863-85-5 (1S,2R,4R)-1-isopropyl-4-methyl-2-(2-methylprop-2-en-1-yloxy)cyclohexane 

Downstream Products

• 753488-83-4 (1S,2R,4R)-2-(2,3-dimethylbut-2-en-1-yloxy)-1-isopropyl-4-methylcyclohexane 
• 195863-85-5 (1S,2R,4R)-1-isopropyl-4-methyl-2-(2-methylprop-2-en-1-yloxy)cyclohexane 
• 2623-23-6 L-menthyl acetate 
• 136375-73-0 [[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]benzene 
• 76358-81-1 tert-butyl(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethylsilane 
• 40940-58-7 (1S,2R,4R)-2-(allyloxy)-1-isopropyl-4-methylcyclohexane 
• 2216-51-5 (-)-menthol 
• 78-79-5 isoprene 

Relevant articles and documents

Allyl, methallyl, prenyl, and methylprenyl ethers as protected alcohols: Their selective cleavage with diphenyldisulfone under neutral conditions

Diphenyldisulfone is a mild and efficient reagent for selective cleavage of methylprenyl (2,3-dimethylbut-2-en-1-yl), prenyl (3-methylbut-2-en1-yl), and methallyl (2-methylallyl) ethers. These reaction conditions are compatible with the presence of other protecting groups such as acetals, acetates, and allyl, benzyl, and TBDMS ethers. Exposure of 2,3-dimethylbut-2-en-1-yl and 3-methylbut-2-en1-yl ethers to diphenyldisulfone led to the formation of 2,3-dimethylbuta-1,3-diene and isoprene, respectively. 2-Methylallyl ethers undergo isomerization to 2-methylpropenyl ethers, which are easily hydrolyzed into the corresponding free alcohols and isobutyraldehyde.