18055-59-9Relevant academic research and scientific papers
Use of cyclohexa-2,5-dien-1-yl-silanes as precursors for gaseous hydrosilanes
-
Paragraph 0053; 0054, (2015/03/18)
The invention relates to the use of cyclohexa-2,5-dien-1-yl-silanes of general formula I for generation of hydrosilanes in solution using a strong Lewis acid. This way, e.g., alkenes can be hydrosilylated in good yields using the cyclohexa-2,5-dien-1-yl-silanes of general formula I as transfer hydrosilylating agents in the presence of a strong Lewis acid as catalyst with concomitant formation of an arene solvent.
USE OF CYCLOHEXA-2,5-DIEN-1-YL-SILANES AS PRECURSORS FOR GASEOUS HYDROSILANES
-
Page/Page column 18; 19, (2015/03/28)
The invention relates to the use of cyclohexa-2,5-dien-1 -yl-silanes of general formula (I), for generation of hydrosilanes in solution using a strong Lewis acid. This way, e.g., alkenes or carbonyl compounds can be hydrosilylated in good yields using the cyclohexa-2,5-dien-1 - yl-silanes of general formula I as transfer hydros! lylating agents in the presence of a strong Lewis acid as catalyst with concomitant formation of an arene solvent.
3-silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: The B(C6F5)3-catalyzed transfer hydrosilylation of alkenes
Simonneau, Antoine,Oestreich, Martin
supporting information, p. 11905 - 11907 (2013/11/19)
Set Me3SiH free! The strong Lewis acid B(C6F 5)3 catalyzes the release of hydrosilanes from 3-silylated cyclohexa-1,4-dienes with concomitant formation of benzene. Subsequent B(C 6F5)3
