54380-53-9

Basic information

• Product Name: cyclohexa-2,5-dien-1-yl(trimethyl)silane
• Synonyms: cyclohexa-2,5-dien-1-yl(trimethyl)silane
• CAS NO: 54380-53-9
• Molecular Weight: 152.312
• Mol File: 54380-53-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: cyclohexa-2,5-dien-1-yl(trimethyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexa-2,5-dien-1-yl(trimethyl)silane(54380-53-9)
• EPA Substance Registry System: cyclohexa-2,5-dien-1-yl(trimethyl)silane(54380-53-9)

Safety Data

• Hazardous Substances Data: 54380-53-9(Hazardous Substances Data)

Upstream product

• 768-32-1 trimethylphenylsilane 
• 75-77-4 chloro-trimethyl-silane 
• 1165952-92-0 cyclohexa-1,4-diene 

Downstream Products

• 956219-35-5 rac-1-cyclohexa-2,4-dien-1-yl-(phenyl)methanol 
• 57266-94-1 (Z)-(1,2-diphenylvinyl)-trimethylsilane 
• 17599-54-1 N-(Trimethylsilyl)-1-phenylethanimin 
• 14629-59-5 diphenylmethyl trimethylsilyl ether 
• 14856-75-8 1-phenyl-1-trimethylsilyloxyethane 
• 18055-59-9 dimethyldiphenethylsilane 
• 10151-74-3 cyclohexyl-trimethyl-silane 
• 18081-22-6 <(Trimethylsilyl)methyl>cyclohexane 
• 18027-28-6 trimethyl(2-phenylpropyl)silane 
• 772-64-5 (phenylethyl)silane 
• 3429-76-3 trimethyl-octyl-silane 
• 993-07-7 trimethylsilan 
• 71-43-2 benzene 
• 927682-00-6 [5,6-bis(benzyloxy)cyclohex-2-en-1-yl](trimethyl)silane 

Relevant articles and documents

Use of cyclohexa-2,5-dien-1-yl-silanes as precursors for gaseous hydrosilanes

The invention relates to the use of cyclohexa-2,5-dien-1-yl-silanes of general formula I for generation of hydrosilanes in solution using a strong Lewis acid. This way, e.g., alkenes can be hydrosilylated in good yields using the cyclohexa-2,5-dien-1-yl-silanes of general formula I as transfer hydrosilylating agents in the presence of a strong Lewis acid as catalyst with concomitant formation of an arene solvent.

3-silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: The B(C6F5)3-catalyzed transfer hydrosilylation of alkenes

Set Me3SiH free! The strong Lewis acid B(C6F 5)3 catalyzes the release of hydrosilanes from 3-silylated cyclohexa-1,4-dienes with concomitant formation of benzene. Subsequent B(C 6F5)3

Sequential desymmetrization-fluorination: Enantioselective synthesis of fluorinated cyclitols

An asymmetric synthesis of enantioenriched, highly functionalized fluorinated carbocycles has been developed based on an enantioselective Sharpless dihydroxylation of cyclohexa-dienylsilanes, combined with a diastereoselective electrophilic fluorodesilyla