18084-97-4

Basic information

• Product Name: chlorotriphenylethylene
• Synonyms: chlorotriphenylethylene;1,1',1''-(1-Chloroethenyl-2-ylidene)trisbenzene;1,1,2-Triphenyl-2-chloroethene;1-Chloro-1,2,2-triphenylethene;1-CHLOROTRIPHENYLETHYLENE
• CAS NO: 18084-97-4
• Molecular Formula: C₂₀H₁₅Cl
• Molecular Weight: 290.7861
• EINECS: 241-992-7
• Mol File: 18084-97-4.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 386.6°Cat760mmHg
• Flash Point: 182.1°C
• Appearance: /
• Density: 1.145g/cm³
• Vapor Pressure: 7.8E-06mmHg at 25°C
• Refractive Index: 1.628
• CAS DataBase Reference: chlorotriphenylethylene(CAS DataBase Reference)
• NIST Chemistry Reference: chlorotriphenylethylene(18084-97-4)
• EPA Substance Registry System: chlorotriphenylethylene(18084-97-4)

Safety Data

• Hazardous Substances Data: 18084-97-4(Hazardous Substances Data)

Usage

General Description

Chlorotriphenylethylene is a chemical compound with the molecular formula C20H15Cl. It is a chlorinated derivative of triphenylethylene, which is a synthetic organic compound. Chlorotriphenylethylene is used in organic synthesis as a building block for various pharmaceuticals and agrochemicals. It is also used as a ligand in metal-catalyzed reactions and as a precursor for the preparation of other organic compounds. This chemical is considered to be a potential endocrine disruptor due to its structural similarity to other compounds known to interfere with hormonal signaling in organisms. Its use and effects are closely monitored and regulated in various industries due to its potential environmental and health impacts.

InChI:InChI=1/C20H15Cl/c21-20(18-14-8-3-9-15-18)19(16-10-4-1-5-11-16)17-12-6-2-7-13-17/h1-15H

Upstream product

• 58-72-0 Triphenylethylene 
• 1733-63-7 1,2,2-triphenylethan-1-one 
• 501-65-5 diphenyl acetylene 
• 98-09-9 benzenesulfonyl chloride 
• 6921-34-2 benzylmagnesium chloride 
• 100-44-7 benzyl chloride 
• 773-47-7 dimethyl benzylphosphonate 
• 109686-85-3 1,2-dichlorotriphenylethane 
• 10026-13-8 phosphorus pentachloride 
• 33885-01-7 1-chloro-2,2,2-triphenylethane 
• 5271-39-6 Triphenylethan 
• 56-23-5 tetrachloromethane 
• 7791-25-5 sulfuryl dichloride 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 1520-42-9 1,1,2-triphenylethane 
• 119-61-9 benzophenone 
• 1040086-20-1 9-chloro-10-phenylphenanthrene 
• 56019-41-1 1-acetoxy-1,2,2-triphenylethene 
• 112349-27-6 9-acetoxy-10-phenylphenanthrene 
• 72989-40-3 buta-1,3-diene-1,1,2,3,4,4-hexaylhexabenzene 

Relevant articles and documents

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Reusable visible light photoredox catalysts; Catalyzed benzylic C(sp 3)-H functionalization/carbocyclization reactions

The C(sp3)-H functionalization/carbocyclization reaction through the oxidative quenching of visible light photoredox catalysts is established for constructing functionalized 1H-indenes. The process is general for a wide range of benzylic C(sps

Reactions on Aromatic Olefins Induced by Aminium Salts: Protic-Acid or Radical Cation Catalyzed Processes

Aromatic olefins by reaction with aminium salts lead, in strongly acidic reaction media, to different reaction products, arising from the intermediate formation of carbocation or radical-cation species.

Organic Gas-Solid Reactions with Stilbenes, Chalcones, and Enamides

Crystalline stilbene (1) adds gaseous chlorine and bromine without intermediate melting.The stereoselectivity is similar to that observed in solutions.Triphenylethene (3) also yields the products 4 in gas-solid reactions with chlorine and bromine, but these products tend to loose HX from the crystal; their conversion products are described.Neither crystalline 1 nor 3, but (E)-1,2-diphenyl-1-propene (7) adds gaseous hydrogen bromide regiospecifically.The same is true for the crystalline chalcone 10, which adds hydrogen bromide and -chloride selectively to give 11 nonisotypically.Gaseous ammonia reconverts crystalline 11 into 10.The enamide 12 in its crystalline state adds the gases hydrogen bromide, -chloride, methanethiol and hydrogen, to give the products 13, but also 15 (addition and condensation) and 16 (double addition). 13f which is formed via hydrogenation of crystals is not isotypical with its precursor 12.The liquid 17 crstallizes on freezing and then easily adds the gases hydrogen bromide (> - 50 deg C) and hydrogen chloride (> - 80 deg C) in highly controlled reactions to give the reactive compounds 18.These are converted not only into oligomers but also into the derivatives 19, 20, 21, and 22.The advantages of the unusual reaction procedures are discussed.