Stereoselective synthesis of the bicyclic core structure of the highly oxidised sesquiterpene neoliacinic acid

DOI: 10.1016/0040-4039(96)01136-7

Source and publish data:

Tetrahedron Letters p. 5605 - 5608 (1996)

Update date:2022-08-02

Topics:

Authors:

Clark, J. Stephen

Dossetter, Alexander G.

Whittingham, William G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01136-7

The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has been constructed in a stereoselective manner by [2,3]-sigmatropic ring-expansion of an oxonium ylide generated catalytically from the α-diazo ketone 4.

Full text of DOI:10.1016/0040-4039(96)01136-7

Products guided by the article

Product name:(S)-1-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-(4-methoxy-benzyloxy)-butan-1-ol

Cas No:180889-64-9

R&D Labs maybe for 180889-64-9

Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
ANGCHEN BRIGHTCHEM CO., LTD

website:http://www.angchenchem.com

Contact:+86-510-88302099 82327577

Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
Jiangsu Zenji Pharmaceuticals LTD

Contact:+86-025-83172562; +1-224-888-1133(USA)

Address:No.5 Xinmofan Road
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK

Relevant to this article

Bu ₄ N ⁺ -Controlled Addition and Olefination with Ethyl 2-(Trimethylsilyl)acetate via Silicon Activation

Doi:10.1055/s-0036-1588805
(2017)
Stereoselective construction of the tricyclic core of neoliacinic acid

Doi:10.1021/jo702111u
(2008)
The reaction of tetrahydrochromeno[3,4-c]pyridines with activated alkynes. the first synthesis of tetrahydrochromeno[4,3-d]azocines

Doi:10.1016/j.tetlet.2011.06.012
(2011)
Synthesis and evaluation of carbocyanine dyes as PRMT inhibitors and imaging agents

Doi:10.1016/j.ejmech.2012.06.017
(2012)
The enantioselective transport of Z-amino acid (Z = benzyloxycarbonyl) and dipeptide K⁺ carboxylates by dipeptide derived lariat ethers

Doi:10.1039/c39900001726
(1990)
First phosphorus macrocycles incorporating tetrathiafulvalene (TTF) moieties

Doi:10.1016/S0040-4039(00)97059-X
(1990)

Article Doi