Tetrahedron Letters p. 5605 - 5608 (1996)
Update date:2022-08-02
Topics:
Clark, J. Stephen
Dossetter, Alexander G.
Whittingham, William G.
The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has been constructed in a stereoselective manner by [2,3]-sigmatropic ring-expansion of an oxonium ylide generated catalytically from the α-diazo ketone 4.
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