Stereoselective synthesis of the bicyclic core structure of the highly oxidised sesquiterpene neoliacinic acid

DOI: 10.1016/0040-4039(96)01136-7

Source and publish data:

Tetrahedron Letters p. 5605 - 5608 (1996)

Update date:2022-08-02

Topics:

Authors:

Clark, J. Stephen

Dossetter, Alexander G.

Whittingham, William G.

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Article abstract of DOI:10.1016/0040-4039(96)01136-7

The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has been constructed in a stereoselective manner by [2,3]-sigmatropic ring-expansion of an oxonium ylide generated catalytically from the α-diazo ketone 4.

Full text of DOI:10.1016/0040-4039(96)01136-7

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