181058-10-6

Basic information

• Product Name: 1,3,5-tris(2'-aminoethyl)-2,4,6-triethylbenzene
• Synonyms: 1,3,5-tris(2'-aminoethyl)-2,4,6-triethylbenzene
• CAS NO: 181058-10-6
• Molecular Weight: 291.48
• Mol File: 181058-10-6.mol

Chemical Properties

• CAS DataBase Reference: 1,3,5-tris(2'-aminoethyl)-2,4,6-triethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tris(2'-aminoethyl)-2,4,6-triethylbenzene(181058-10-6)
• EPA Substance Registry System: 1,3,5-tris(2'-aminoethyl)-2,4,6-triethylbenzene(181058-10-6)

Safety Data

• Hazardous Substances Data: 181058-10-6(Hazardous Substances Data)

Upstream product

• 142183-78-6 1,3,5-tris(chloromethyl)-2,4,6-triethylbenzene 
• 102-25-0 1,3,5-triethylbenzene 
• 181058-08-2 1,3,5-tris(bromomethyl)-2,4,6-triethylbenzene 
• 181058-09-3 1,3,5-tris(cyanomethyl)-2,4,6-triethylbenzene 

Downstream Products

• 1020075-08-4 C₄₅H₇₈N₆O₉ 

Relevant articles and documents

Pyrrolic tripodal receptors effectively recognizing monosaccharides. Affinity assessment through a generalized binding descriptor

Pyrrolic and imino (3) or amino (4) H-bonding ligands were incorporated into a benzene-based tripodal scaffold to develop a new generation of receptors for molecular recognition of carbohydrates. Receptors 3 and 4 effectively bound a set of octylglycoside

Tripodal (N-alkylated) CMP(O) and malonamide ligands: Synthesis, extraction of metal ions, and potentiometric studies

Tripodal ligands build on the C-pivot (9b-e, 13b-d, and 17a-d) and trialkylbenzene platforms (10a,b, 11, 12, 14a,b, and 18a,b) bearing (N-alkylated) carbamoylmethylphosphine oxide (CMPO), carbamoylmethylphosphonate (CMP), and malonamide moieties were synt

Control of functional group proximity and direction by conformational networks: Synthesis and stereodynamics of persubstituted arenes

The cooperative nonbonded interactions present in hexaethylbenzene result in an arrangement of alkyl groups such that the 1,3,5 and 2,4,6 substituents point to opposite faces of the benzene ring. Correspondingly, derivatives of hexaethylbenzene have their functional groups convergent (meta as in 1,3,5-trisubstituted-2,4,6-triethylbenzene) or divergent (ortho, para as in 1,2-disubstituted-3,4,5,6-tetraethylbenzenes or 1,4-disubstituted-2,3,5,6-tetraethylbenzenes) due to this cooperative conformational network. To illustrate this structural feature and probe its dynamics, 1,4-di-X-2,3,5,6-tetraethylbenzenes have been synthesized. The dynamic stereochemistry of the disubstituted compounds has been studied by variable temperature 1H NMR spectroscopy. Using the same strategy, the 1,3,5-tris(CH2Y)-2,4,6-triethylbenzenes have also been prepared. The steric bulk of the substituent in the disubstituted compounds has been found to influence the barrier height. The trends found are applicable for the use of these compounds as angular building blocks for the design of ligands, polymers, and supramolecular architectures.

Synthesis of 1,3,5-Tris(bromomethyl)-2,4,6-triethylbenzene - a Versatile Precursor To Predisposed Ligand

The previously unknown title compound was prepared by means of exhaustive bromomethylation of 1,3,5-triethylbenzene.It was used as a starting molecule in the synthesis of ligands carrying three thiourea groups.A predisposition of such ligands in an ababab-manner referring to the orientation of the substituents was confirmed by X-structure determination.