18120-99-5Relevant academic research and scientific papers
Bio-heterogeneous Cu(0)NC@PHA for n-aryl/alkylation at room temperature
Jian Fui, Choong,Lutfor Rahman, Md,Musta, Baba,Sani Sarjadi, Mohd,Sarkar, Shaheen M.,Xin Ting, Tang
, (2021/06/28)
A pure cellulose was derived from waste fibre and it was chemically modified to a hydroxamic acid ligand. The poly(hydroxamic acid) was treated with an aqueous copper solution to afford the greenish stable five-membered copper complex; namely Cu(II)@PHA. Further, the Cu(II)@PHA was treated with a reducing agent hydrazine hydride to give brown colour cellulose supported copper nanocomplex (Cu(0)NC@PHA). The Cu(0)NC@PHA was characterised by ATR-FTIR, FE-SEM & EDS, TEM, ICP-OES, TGA, XRD and XPS analyses. The cellulose-based Cu(0)NC@PHA was used for the n-aryl/alkylation (Michael addition) reaction with a variety of α,β-unsaturated Michael acceptors to produce the corresponding n-aryl/alkyl products with an excellent yield at room temperature. The Cu(0)NC@PHA showed extraordinary stability and it was easily filtered out from the reaction mixture and may potentially recycled up to five times without loss of its original catalytic ability.
Solvent free base catalysis and transesterification over basic functionalised Metal-Organic Frameworks
Savonnet, Marie,Aguado, Sonia,Ravon, Ugo,Bazer-Bachi, Delphine,Lecocq, Vincent,Bats, Nicolas,Pinel, Catherine,Farrusseng, David
experimental part, p. 1729 - 1732 (2011/03/20)
Metal-Organic Frameworks (post-)functionalised with nitrogen containing moieties undergo solvent free aza-Michael condensation and transesterification, surpassing molecular and functionalised MCM-type analogues. The Royal Society of Chemistry 2009.
Polyvinyl pyridine as a novel solid heterogeneous, recyclable catalyst for aza-Michael reaction
Raje, Vivek P.,Bhat, Ramakrishna P.,Samant, Shriniwas D.
, p. 2676 - 2678 (2008/09/16)
Polyvinyl pyridine (PVP) is prepared by radical polymerization of 4-vinyl pyridine. PVP was used as a heterogeneous basic catalyst for the aza-Michael reaction of secondary amines and carbamates with α,β-unsaturated esters, cyanides and ketones to obtain the corresponding adducts in excellent yields (70-90%). Georg Thieme Verlag Stuttgart.
