181480-92-2

Upstream product

• 6748-85-2 methyl 2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 2280-44-6 D-Glucose 

Downstream Products

• 335239-64-0 Benzoic acid (2S,3R,4S,6S)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-difluoromethylene-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Highly regio- and stereo-selective alkyl substitution with copper reagents for the construction of chiral trifluoromethylated quaternary carbon centres

A new route for the asymmetric construction of quaternary carbon centres containing a trifluoromethyl group has been established using a highly regio- and stereo-selective SN2′ reaction of organocopper and organocuprate reagents with allylic mesylates 4 and 8.