1816-96-2Relevant academic research and scientific papers
Patterns of soft C - H...O hydrogen bonding in diaryl sulfones
Glidewell, Christopher,Harrison, William T. A.,Low, John N.,Sime, Jamie G.,Wardell, James L.
, p. 190 - 200 (2001)
In bis(4-tolyl) sulfone, C14H14O2S (1), 2,5,4′-trimethyldiphenyl sulfone, C15H16O2S (2), and 4-chlorodiphenyl sulfone, C12H9ClO2S (3), the molecules are lin
The synthesis of diarylsulfones with simple arenes and K2S2O8 through double C-S bond formation
Yang, Yiqing,Chen, Zhang,Rao, Yu
supporting information, p. 15037 - 15040 (2014/12/11)
An unprecedented double C-S bond formation method has been developed to prepare both symmetric and unsymmetric diarylsulfones with simple arenes in a single step. This represents the first example that K2S2O8 can be employed as a highly effective sulfonating agent to synthesize diarylsulfones. The reaction demonstrates excellent reactivity, good functional group tolerance and high yields.
Sulfonylation of aromatic compounds with methyl p-toluenesulfonate as a sulfonylating precursor
Khodaei,Nazari
, p. 507 - 512 (2013/02/22)
We have developed Friedel-Crafts (FC) sulfonylation of aromatic compounds with methyl p-toluenesulfonate as a sulfonylating precursor. In this procedure, methyl p-toluenesulfonate was treated and activated with pyridine to produce N-methylpyridinium p-toluenesulfonate as a sulfonylation reagent. Reactivity of this salt for the sulfonylation of mesitylene was investigated in the presence of three different promoters, such as triflic anhydride, dimethylsulfide ditriflate, and triphenylphosphine ditriflate (TPPD). All of the promoters show chemoselectivity and among them, TPPD presents a chemoselectivity in FC sulfonylation. Iranian Chemical Society 2012.
MoO2Cl2 as a novel catalyst for Friedel-Crafts acylation and sulfonylation
de Noronha, Rita G.,Fernandes, Ana C.,Rom?o, Carlos C.
experimental part, p. 1407 - 1410 (2009/06/18)
The use of MoO2Cl2 as a novel catalyst for Friedel-Crafts acylation and sulfonylation is described. A series of aromatic ketones and sulfones were prepared in moderate to good yields using acyl chloride or sulfonyl chloride in the presence of MoO2Cl2 (20 mol %), under solvent-free conditions.
Sulfonylation of arenes with sulfonamides
Yao, Bangben,Zhang, Yuhong
, p. 5385 - 5388 (2008/12/21)
In the presence of triflic anhydride, sulfonylation of arenes with sulfonamides proceeded smoothly in Cl2CHCHCl2 at 80-140 °C, which gave rise to the desired products in good to excellent yields.
Highly selective catalytic Friedel-Crafts sulfonylation of aromatic compounds using a FeCl3-based ionic liquid
Bahrami, Kiumars,Khodei, Mohammad Mehdi,Shahbazi, Fomeida
, p. 3931 - 3934 (2008/09/21)
Friedel-Crafts sulfonylation of aromatic compounds was carried out using FeCl3-based ionic liquid. These liquids serve as efficient media as well as Lewis acid catalyst.
Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal
Jang, Doo Ok,Moon, Kyung Soo,Cho, Dae Hyan,Kim, Joong-Gon
, p. 6063 - 6066 (2007/10/03)
The Friedel-Crafts acylation of activated benzenes with various aromatic and aliphatic acid chlorides was studied in the presence of indium metal. The reaction was accomplished in high isolated yields under solvent or solvent-less conditions. The method is also applicable for preparing diaryl sulfones from aromatic compounds and aryl sulfonyl chlorides.
A practical and efficient method for the preparation of aromatic sulfones by the reaction of aryl sulfonyl chlorides with arenes catalysed by Fe(OH) 3
Jin, Tongshou,Zhao, Ying,Ma, Yanran,Li, Tongshuang
, p. 2183 - 2185 (2007/10/03)
Fe (OH)3 catalyses Friedel-Crafts sulfonylation of arenes with aryl sulfonyl chlorides to obtain the corresponding diaryl sulfones in good yields.
Fe-pillared bentonite-an efficient catalyst for sulfonylation of arenes using aryl and alkyl sulfonyl chlorides
Singh, Devendrapratap U.,Singh, Pankajkumar R.,Samant, Shriniwas D.
, p. 9079 - 9082 (2007/10/03)
Fe-pillared bentonite (Fe-PILC) was shown to be an extremely efficient catalyst for the sulfonylation of activated as well as unactivated carbocyclic aromatic compounds and heterocyclic aromatic compounds. The catalyst was also found to be recyclable.
Antimony(V) chloride-benzyltriethylammonium chloride complex as an efficient catalyst for friedel-crafts acylation reactions
Huang, An-Ping,Liu, Xue-Yuan,Li, Lian-Hua,Wu, Xiao-Li,Liu, Wei-Min,Liang, Yong-Min
, p. 599 - 602 (2007/10/03)
A novel catalytic system, the complex of antimony(V) chloride (SbCl 5) and benzyltriethylammonium chloride (TEBA), C6H 5CH2NEt3(SbCl5)2Cl complex, is described for Friedel-Crafts acylation reactions of aromatics with acyl and sulfonyl chlorides. The catalyst has a number of useful characteristics, such as ready access, minimal toxicity, reusability, insensitivity to atmosphere and moisture, rapid acylation with high yield, and ease of operation.
