18171-30-7

Basic information

• Product Name: Silane, chlorodimethyl(trichloromethyl)-
• CAS NO: 18171-30-7
• Molecular Formula: C3H6Cl4Si
• Molecular Weight: 211.978
• Mol File: 18171-30-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, chlorodimethyl(trichloromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, chlorodimethyl(trichloromethyl)-(18171-30-7)
• EPA Substance Registry System: Silane, chlorodimethyl(trichloromethyl)-(18171-30-7)

Safety Data

• Hazardous Substances Data: 18171-30-7(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 56-23-5 tetrachloromethane 
• 6376-86-9 dimethylsilylene 
• 67-66-3 chloroform 
• 75-78-5 dimethylsilicon dichloride 
• 4218-23-9 (trichloromethyl)methyldichlorosilane 
• 13528-88-6 1,1,2-trichloro-1,2,2-trimethyldisilane 

Relevant articles and documents

Complexation of paramagnetic intermediates formed in the photolysis of 7,7-dimethyl-1,4,5,6-tetraphenyl-2,3-benzo-7-silanorbornadiene: A study by spin chemistry methods

Complexation of paramagnetic intermediates formed in the photolysis of 7,7-dimethyl-1,4,5,6-tetraphenyl-2,3-benzo-7-silanorbornadiene with n-donors (PPh3, O2) was studied by spin chemistry methods.

CONVERSION OF DISILANES TO FUNCTIONAL MONOSILANES XIV. REACTIONS OF METHYLCHLORODISILANES WITH gem-POLYHALIDES CATALYZED BY ORGANIC BASES

The reaction of methylchlorodisilanes with gem-polyhalides in the presence of organic bases has been investigated.The compounds CXCl2SiMeCl2 (X = Cl, H, F and SiMeCl2) were obtained in moderate to high yields from Cl2MeSiSiMeCl2 and polyhalomethanes (e.g., CCl4, CHCl3, CFCl3 and CCl3SiMeCl2) with PPh3 or Bu4NCl as catalyst.The reaction of 1,1,2-trichlorotrimethyldisilane with CCl4 afforded a 1:1 mixture of CCl3SiMeCl2 and CCl3SiMe2Cl.Also, XC6H4CCl2SiMeCl2 (X = H and 4-Cl) were obtained in moderate yields from Cl2MeSiSiMeCl2 and XC6H4CCl3 with Bu4NCl or Bu4NF as catalyst.