18192-48-8Relevant academic research and scientific papers
Preparation of silyl-substituted dizinciomethanes and their reactions with electrophiles
Matsubara, Seijiro,Otake, Yasuyuki,Morikawa, Takuya,Utimoto, Kiitiro
, p. 1315 - 1316 (1998)
Silyl-substituted bis(bromozincio)methanes (RMe2Si-CH(ZnBr)2; R = Me, Ph, and p-MeO-C6H4), prepared from the corresponding dibromides by Pb catalyzed reaction with zinc, reacted stepwise with two different electrophiles, R1X and E+, yielding R1- CH(SiMe2R)-E.
Synthesis of β-silylated olefins from α,β-unsaturated aldehydes and ketones
Bolourtchian,Mojtahedi,Saidi
, p. 590 - 591 (2007/10/03)
α,β-Unsaturated aldehydes and ketones such as phorone, benzalacetone, benzalacetophenone, 4-(2-furyl)-3-buten-4-one and β-ionone, react with TMS-Cl in the presence of Li in THF to give conjugated β-silylated enoxysilanes. Hydrolysis of this compounds in a
