18207-24-4Relevant articles and documents
Magnesium-promoted reductive silylation and acylation of tropone and tropone acetal
Maekawa, Hirofumi,Nagakubo, Keisuke,Nishi, Midori,Nishimura, Makoto,Nagahara, Daisuke
, p. 1183 - 1189 (2013/11/19)
Magnesium-promoted reductive coupling of chlorotrialkylsilanes and tropone or tropone acetal in DMF, followed by oxidation with 2,3-dichloro-5,6-dicyano-1, 4-benzoquinone in benzene gives 2-trialkylsilyltropones as the main product, and the reductive coup
ANODIC TRANSFORMATION OF CYCLOHEPTATRIENE TO TROPONE AND TROPOLONE
Shono, Tatsuya,Nozoe, Tetsuo,Maekawa, Hirofumi,Kashimura, Shigenori
, p. 555 - 558 (2007/10/02)
Cycloheptatriene (CHT) has been directly transformed to 7-methoxycycloheptatriene (7-MCHT), an equivalent compound to a tropolium salt, by the anodic oxidation of CHT in methanol.The further anodic oxidation of 3-MCHT prepared from 7-MCHT has been found to be an effective method of synthesis of tropone and tropolone.