18212-22-1

Basic information

• Product Name: 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE
• Synonyms: METHYL 4-(1,2,3-THIADIAZOL-4-YL)PHENYL ETHER;4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE;4-(4-Methoxyphenyl)-1,2,3-thiadiazole ,97%;4-(4-methoxyphenyl)thiadiazole
• CAS NO: 18212-22-1
• Molecular Formula: C₉H₈N₂OS
• Molecular Weight: 192.24
• Mol File: 18212-22-1.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 328.4 °C at 760 mmHg
• Flash Point: 152.4 °C
• Appearance: /
• Density: 1.243 g/cm³
• Vapor Pressure: 0.000364mmHg at 25°C
• Refractive Index: 1.588
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE(18212-22-1)
• EPA Substance Registry System: 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE(18212-22-1)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 22-36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 18212-22-1(Hazardous Substances Data)

Usage

Chemical Properties

Orange solid

InChI:InChI=1/C9H8N2OS/c1-12-8-4-2-7(3-5-8)9-6-13-11-10-9/h2-6H,1H3

Upstream product

• 120445-97-8 C₁₀H₁₃N₃O₂ 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 1592482-76-2 N′-(2-chloro-1-(4-methoxyphenyl)ethylidene)benzohydrazide 
• 2196-99-8 2-chloro-1-(4-methoxyphenyl)ethanone 
• 32117-52-5 1-(1-(4-methoxyphenyl)ethylidene)-2-tosylhydrazine 
• 1402671-84-4 C₁₈H₂₇N₄O₃S⁽¹⁺⁾*CF₃O₃S^(1-) 
• 25445-81-2 N-ethoxycarbonyl-(4-methoxyacetophenone)hydrazone 

Downstream Products

• 54671-35-1 4-(4-Methoxy-phenyl)-2-[1-(4-methoxy-phenyl)-meth-(Z)-ylidene]-[1,3]dithiole 
• 140241-19-6 2-phenylimino-4-p-methoxyphenyl-1,3-thiaselenole 
• 59834-05-8 4-(4'-hydroxyphenyl)-1,2,3-thiadiazole 
• 132606-85-0 2-(4-Methoxy-phenylethynylsulfanyl)-1,1-diphenyl-ethanol 
• 132606-86-1 1-(4-Methoxy-phenylethynylsulfanyl)-2-phenyl-propan-2-ol 
• 132606-80-5 1-(4-Methoxy-phenylethynylsulfanyl)-propan-2-one 
• 93515-92-5 N-[4-(4-Methoxy-phenyl)-[1,3]dithiol-(2Z)-ylidene]-acetamide 
• 93515-90-3 N-[4-(4-Methoxy-phenyl)-[1,3]dithiol-(2Z)-ylidene]-benzamide 
• 132606-79-2 2-(4-Methoxy-phenylethynylsulfanyl)-1-phenyl-ethanone 
• 93515-93-6 [4-(4-Methoxy-phenyl)-[1,3]dithiol-(2Z)-ylidene]-carbamic acid ethyl ester 
• 150398-93-9 (E)-thiokohlensaeure-O-ethyl-S-<2-(4-methoxyphenyl)ethenyl>-diester 
• 80676-02-4 potassium 2-p-methoxyphenylethynethiolate 
• 93515-91-4 N-[4-(4-Methoxy-phenyl)-[1,3]dithiol-(2Z)-ylidene]-4-methyl-benzamide 
• 18212-49-2 1-Ethoxycarbonylthio-2-p-methoxy-phenylethin 

Relevant articles and documents

Metal- and Oxidant-free Electrosynthesis of 1,2,3-Thiadiazoles from Element Sulfur and N-tosyl Hydrazones

A metal- and oxidant-free electrochemical method for synthesizing 1,2,3-thiadiazoles by inserting element sulfur into N-tosyl hydrazones is reported. This electrochemical transformation engages electrons as reagents to achieve redox processes, and avoid e

Selective transformations of 2-(p-toluenesulfonyl)-N-tosylhydrazones to substituted 1,2,3-thiadiazoles

Selective transformations of 2-(p-toluenesulfonyl)-N-tosylhydrazones with different sulfur sources have been established. A series of 4-aryl-1,2,3-thiadiazoles and novel 4-aryl-5-tosyl-1,2,3-thiadiazoles were selectively constructed by the adjustment of reaction conditions. These protocols feature short reaction time, good compatibility of functional group, easily available materials, and good selectivity.

Preparation method of thiadiazole containing aryl group and alkyl group

The invention discloses a preparation method of thiadiazole containing an aryl group and an alkyl group. Methyl ketone, p-toluenesulfonhydrazide and potassium thiocyanate which are used as a substrateundergo a three-component one-pot reaction in DMSO used