182167-81-3Relevant academic research and scientific papers
Synthesis of and molecular dynamics simulations on a tetrasaccharide corresponding to the repeating unit of the capsular polysaccharide from Salmonella enteritidis
Olsson, Johan D. M.,Landstroem, Jens,Roennols, Jerk,Oscarson, Stefan,Widmalm, Goeran
experimental part, p. 1612 - 1618 (2009/06/28)
Syntheses of two oligosaccharides as methyl glycosides related to the repeating unit of S. enteritidis capsular polysaccharide (CPS) are presented. The trisaccharide corresponds to the backbone of the CPS whereas the tetrasaccharide is a model for the rep
Preparation of disaccharide haptens corresponding to Salmonella serogroups B and D
Zegelaar-Jaarsveld, Korien,Van Der Plas, Simon C.,Van Der Marel, Gijs A.,Van Boom, Jacques H.
, p. 665 - 689 (2007/10/03)
The properly protected ethyl 1-thio-abequopyranoside 11 and ethyl 1-thio-tyvelo-pyranoside 26 were prepared by a sequence of reactions, the key step of which was the regioselective hydride-mediated ring-opening of the cyclic sulfate function in compounds 8 and 18. Iodonium ion-assisted glycosylation of allyl mannopyranoside 30 with the individual ethyl 3,6-dideoxy-1-thio-D-hexopyranoside donors 11 and 26 furnished, after deprotection, the respective allyl 3-O-(α-D-abequopyranosyl)-α-D-mannopyranoside 1 and allyl 3-O-(α-D-tyvelopyranosyl)-α-D-mannopyranoside 2.
