32476-35-0

Upstream product

• 14133-63-2 methyl 2,3-O-isopropylidene-α-D-rhamnopyranoside 
• 182167-71-1 Methyl 2,3-O-isopropylidene-4-O-(p-methoxybenzyl)-α-D-rhamnopyranoside 
• 182167-73-3 Methyl 4-O-(p-methoxybenzyl)-α-D-rhamnopyranoside 
• 112612-45-0 methyl 2,3-O-isopropylidene-6-O-p-toluenesulfonyl-α-D-mannopyranoside 
• 98-88-4 benzoyl chloride 
• 182167-79-9 Benzoic acid (2S,3S,5S,6R)-5-hydroxy-2-methoxy-6-methyl-tetrahydro-pyran-3-yl ester 
• 58056-38-5 methyl 4-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranoside 
• 182167-72-2 Toluene-4-sulfonic acid (3aS,4S,6R,7R,7aS)-4-methoxy-7-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-ylmethyl ester 
• 182167-77-7 Benzoic acid (2S,3S,5S,6R)-2-methoxy-5-(4-methoxy-benzyloxy)-6-methyl-tetrahydro-pyran-3-yl ester 
• 182167-74-4 Methyl 4-O-(p-methoxybenzyl)-2,3-O-sulfonyl-α-D-rhamnopyranoside 

Downstream Products

• 82086-29-1 2,4-di-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranosyl chloride 
• 182167-80-2 1-O-Acetyl 2,4-di-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranose 
• 82086-32-6 8-methoxycarbonyloctyl 4,6-O-cyclohexylidene-3-O-(2,4-di-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranosyl)-2-O-(tetra-O-benzyl-α-D-galactopyranosyl)-α-D-mannopyranoside 
• 182167-81-3 ethyl 2,4-di-O-benzoyl-3,6-dideoxy-1-thio-α-D-arabino-hexopyranoside 
• 182167-82-4 ethyl 2,4-di-O-benzoyl-3,6-dideoxy-1-thio-β-D-arabino-hexopyranoside 
• 182167-86-8 Allyl 2-O-benzoyl-3-O-[2,4-di-O-benzoyl-3,6-dideoxy-4-O-(p-methoxybenzyl)-α-D-arabino-hexopyranosyl]-4,6-di-O-(p-methoxybenzyl)-α-D-mannopyranoside 
• 182167-87-9 Allyl 2-O-benzoyl-3-O-(2,4-di-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranosyl)-α-D-mannopyranoside 

Relevant academic research and scientific papers

Synthesis of three Salmonella epitopes for biosensor studies of carbohydrate-antibody interactions

Disaccharides 1-3 corresponding to the antigenic determinants of Salmonella serotypes A, B, and D1 were synthesized in a form suited for use in biosensors. The disaccharide determinants each contain a unique 3,6-dideoxyhexose, namely abequose (

Preparation of disaccharide haptens corresponding to Salmonella serogroups B and D

The properly protected ethyl 1-thio-abequopyranoside 11 and ethyl 1-thio-tyvelo-pyranoside 26 were prepared by a sequence of reactions, the key step of which was the regioselective hydride-mediated ring-opening of the cyclic sulfate function in compounds 8 and 18. Iodonium ion-assisted glycosylation of allyl mannopyranoside 30 with the individual ethyl 3,6-dideoxy-1-thio-D-hexopyranoside donors 11 and 26 furnished, after deprotection, the respective allyl 3-O-(α-D-abequopyranosyl)-α-D-mannopyranoside 1 and allyl 3-O-(α-D-tyvelopyranosyl)-α-D-mannopyranoside 2.

Antigenic determinants of Salmonella serogroups A and D1. Synthesis of trisaccharide glycosides for use as artificial antigens.

The disaccharide glycoside 8-methoxycarbonyloctyl 4,6-O-cyclohexylidine-2-O-(tetra-O-benzyl-alpha-D-galactopyranosyl)-alpha-D-manno pyranoside (7) was used as a common intermediate to the trisaccharide determinants of both Salmonella serogroups A and D1.