63196-76-9

Basic information

• Product Name: Cyclopropanecarboxylic acid, 2-(phenylthio)-, methyl ester
• CAS NO: 63196-76-9
• Molecular Formula: C11H12O2S
• Molecular Weight: 208.281
• Mol File: 63196-76-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclopropanecarboxylic acid, 2-(phenylthio)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanecarboxylic acid, 2-(phenylthio)-, methyl ester(63196-76-9)
• EPA Substance Registry System: Cyclopropanecarboxylic acid, 2-(phenylthio)-, methyl ester(63196-76-9)

Safety Data

• Hazardous Substances Data: 63196-76-9(Hazardous Substances Data)

Upstream product

• 6832-16-2 methyl diazoacetate 
• 1822-73-7 phenylthioethylene 
• 65248-39-7 Methyl 2-cyclopropene-1-carboxylate 
• 108-98-5 thiophenol 
• 29193-71-3 methyl 4-(phenylsulfanyl)butanoate 

Downstream Products

• 80398-84-1 (E)-2-(hydroxymethyl)cyclopropyl phenyl sulphide 
• 80398-95-4 Trimethyl-[(1S,2S)-2-phenylsulfanyl-2-((E)-styryl)-cyclopropylmethoxy]-silane 
• 80398-93-2 [(1S,2S)-2-((E)-Hex-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-trimethyl-silane 
• 80399-05-9 Trimethyl-((1E,4E)-4-phenylsulfanyl-nona-1,4-dienyloxy)-silane 
• 80398-92-1 Trimethyl-[(1S,2S)-2-((E)-pent-1-enyl)-2-phenylsulfanyl-cyclopropylmethoxy]-silane 
• 80399-06-0 Trimethyl-((1E,4E)-4-phenylsulfanyl-deca-1,4-dienyloxy)-silane 
• 80398-89-6 Trimethyl-[(1S,2S)-2-phenylsulfanyl-2-((E)-propenyl)-cyclopropylmethoxy]-silane 
• 80399-01-5 Trimethyl-((1E,4E)-4-phenylsulfanyl-hepta-1,4-dienyloxy)-silane 
• 80398-85-2 (1S,5R)-1-Phenylsulfanyl-3-oxa-bicyclo[3.1.0]hexan-2-ol 
• 80398-96-5 (E)-5-[(1S,2S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1-phenylsulfanyl-cyclopropyl]-pent-4-enoic acid ethyl ester 
• 80399-14-0 (5E,8E)-9-(tert-Butyl-dimethyl-silanyloxy)-6-phenylsulfanyl-nona-5,8-dienoic acid ethyl ester 
• 80399-17-3 (E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane 
• 80398-94-3 tert-Butyl-dimethyl-[(1S,2S)-2-phenylsulfanyl-2-((E)-styryl)-cyclopropylmethoxy]-silane 
• 80399-18-4 (X,E)-2-<7-<(trimethylsilyl)oxy>-4-thiophenyl-3,6-heptadienyl>-2-methyl-1,3-dioxolane 

Relevant articles and documents

Bifunctional Cyclopropyl Reagents: Stereocontrolled Approach to Vinyl Sulfides and Chemodifferentiated 1,4-Dicarbonyl Systems

The use of (E)-2-(hydroxymethyl)cyclopropyl phenyl sulfide as a useful conjunctive reagent, particularly in a stereocontrolled synthesis of vinyl sulfides, is reported.

STRAIN AND SELECTIVITY: PARTNERS FOR ORGANIC SYNTHESIS

The development of two new small-ring conjunctive reagents, (E)-2-(hydrohymethyl)cyclopropyl phenyl sulphide and 1,1-bis(benzenesulphonyl)cyclopropane, are reported.The former permits a synthesis of 2,4-disubstituted cyclobutanones and (E)-4-phenylthio-4-