182306-79-2

Upstream product

• 75-36-5 acetyl chloride 
• 181022-82-2 (3aS,4R,7S,7aR)-4,8,8-Trimethyl-1-phenyl-octahydro-4,7-methano-benzoimidazol-2-one 

Downstream Products

• 182306-93-0 (3aS,4R,7S,7aR)-3-((E)-(R)-3-Hydroxy-5-phenyl-pent-4-enoyl)-4,8,8-trimethyl-1-phenyl-octahydro-4,7-methano-benzoimidazol-2-one 
• 182509-76-8 (3aS,4R,7S,7aR)-3-((S)-3-Hydroxy-4-methyl-pentanoyl)-4,8,8-trimethyl-1-phenyl-octahydro-4,7-methano-benzoimidazol-2-one 
• 182509-77-9 (3aS,4R,7S,7aR)-3-((S)-3-Hydroxy-4,4-dimethyl-pentanoyl)-4,8,8-trimethyl-1-phenyl-octahydro-4,7-methano-benzoimidazol-2-one 
• 182509-75-7 (3aS,4R,7S,7aR)-3-((S)-3-Hydroxy-5-methyl-hex-4-enoyl)-4,8,8-trimethyl-1-phenyl-octahydro-4,7-methano-benzoimidazol-2-one 

Relevant academic research and scientific papers

New chiral acetate imide enolate for stereoselective aldol reactions

The chiral imide acetate 4 reacts upon lithium and titanium enolate formation conditions with aldehydes in a stereoselective manner. Remarkably, aldols obtained from aromatic and α,β-unsaturated aldehydes exhibited opposite stereochemistry than those obtained from aliphatic aldehydes.