Tetrahedron Letters p. 6931 - 6934 (1996)
Update date:2022-07-30
Topics:
Palomo, Claudio
Oiarbide, Mikel
Gonzalez, Alberto
Garcia, Jesus M.
Berree, Fabienne
Linden, Anthony
The chiral imide acetate 4 reacts upon lithium and titanium enolate formation conditions with aldehydes in a stereoselective manner. Remarkably, aldols obtained from aromatic and α,β-unsaturated aldehydes exhibited opposite stereochemistry than those obtained from aliphatic aldehydes.
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