18232-09-2Relevant academic research and scientific papers
Use of Sulfoxides as Cocatalysts in the Palladium-Quinone-Catalyzed 1,4-Diacetoxylation of 1,3-Dienes. An Example of Ligand-Accelerated Catalysis
Grennberg, Helena,Gogoll, Adolf,Baeckwall, Jan-E.
, p. 5808 - 5811 (2007/10/02)
The use of sulfinyl quinones as cocatalysts in the palladium-catalyzed 1,4-diacetoxylation of 1,3-dienes improves the stereochemical outcome of the reaction by increasing the rate of the internal migration of the acetate nucleophile.A mechansim of the int
