18268-10-5

Basic information

• Product Name: salicylaldehyde diphenyl dithioacetal
• Synonyms: salicylaldehyde diphenyl dithioacetal
• CAS NO: 18268-10-5
• Molecular Weight: 324.467
• Mol File: 18268-10-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: salicylaldehyde diphenyl dithioacetal(CAS DataBase Reference)
• NIST Chemistry Reference: salicylaldehyde diphenyl dithioacetal(18268-10-5)
• EPA Substance Registry System: salicylaldehyde diphenyl dithioacetal(18268-10-5)

Safety Data

• Hazardous Substances Data: 18268-10-5(Hazardous Substances Data)

Upstream product

• 90-02-8 salicylaldehyde 
• 108-98-5 thiophenol 
• 126-81-8 dimedone 
• 89-95-2 2-methyl-benzyl alcohol 

Downstream Products

• 90-02-8 salicylaldehyde 
• 4265-25-2 2-methylbenzofuran 
• 4265-14-9 2-benzylbenzofuran 
• 40485-03-8 2-(2'-phenylethyl)benzo[b]furan 
• 1839-72-1 2-phenylbenzofuran 
• 14949-49-6 2,3-dihydro-1-benzoxep-4-ene 
• 295785-51-2 1-(Bis-phenylsulfanyl-methyl)-2-(3-methyl-but-3-enyloxy)-benzene 
• 292081-10-8 [2-(bis-phenylsulfanyl-methyl)-phenoxy]-tert-butyl-dimethyl-silane 

Relevant articles and documents

Graphene oxide (GO)-catalyzed chemoselective thioacetalization of aldehydes under solvent-free conditions

An efficient method for the synthesis of open chain, cyclic, and unsymmetrical dithioacetals from aryl/hetero-aryl/aliphatic aldehydes is described. The reaction is performed using graphene oxide (GO) as the catalyst under solvent-free and aerobic conditions. High chemoselectivity is observed in the reaction as aryl/alkyl ketones do not give thioketals under the condition.

Alkylidenation of esters on solid support and traceless synthesis of 2- substituted benzofurans

Polymer-supported esters are smoothly converted into enol ethers using a titanocene alkylidene prepared by treatment of 2-tert- butyldimethylsilyloxybenzaldehyde diphenyldithioacetal with the low valent titanium species Cp2Ti[P(OEt)3]2. Treatment of the enol ethers with acid leads to the release of ketones from the Wang resin in high yield. Traceless solid-phase synthesis of 2-substituted benzofurans is achieved in a three- step termination procedure. (C) 2000 Published by Elsevier Science Ltd.