18276-79-4

Basic information

• Product Name: diethyl (1-(4-iodophenyl)vinyl)phosphate
• CAS NO: 18276-79-4
• Molecular Weight: 382.135
• Mol File: 18276-79-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diethyl (1-(4-iodophenyl)vinyl)phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl (1-(4-iodophenyl)vinyl)phosphate(18276-79-4)
• EPA Substance Registry System: diethyl (1-(4-iodophenyl)vinyl)phosphate(18276-79-4)

Safety Data

• Hazardous Substances Data: 18276-79-4(Hazardous Substances Data)

Upstream product

• 31827-94-8 2-bromo-1-(4-iodophenyl)ethanone 
• 122-52-1 triethyl phosphite 
• 13329-40-3 4-Iodoacetophenone 
• 814-49-3 diethyl chlorophosphate 
• 4209-04-5 2-chloro-1-(4-iodophenyl)ethan-1-one 

Relevant articles and documents

Selective Alkenylation and Hydroalkenylation of Enol Phosphates through Direct C-H Functionalization

An efficient and selective Rh-catalyzed direct C-H functionalization reaction of enol phosphates was developed. The method is applicable to a variety of coupling partners, including activated alkenes, alkynes, and allenes, and leads to the formation of various valuable alkenylated and hydroalkenylated enol phosphates through the action of the phosphate directing group. The versatility and utility of the coupling products were demonstrated through further transformations into synthetically useful building blocks. P points the way: A direct C-H functionalization of enol phosphates was developed. The method is applicable to a variety of coupling partners, including activated alkenes, alkynes, and allenes, and it leads to the formation of alkenylated and hydroalkenylated enol phosphates through the action of the phosphate directing group. The utility of the coupling products are demonstrated by further transformations into synthetically useful building blocks.