182884-09-9Relevant academic research and scientific papers
Facile synthetic entry into the 1,3-dihydro-3-methyl-3-phenyl-1,2-benziodoxole family of λ3-iodanes
Rabah, Ghada A.,Koser, Gerald F.
, p. 6453 - 6456 (1996)
The synthesis of a series of 1,3-dihydro-3-methyl-3-phenyl-1,2-benziodoxoles, 7, containing chloro, tosyloxy, acetoxy, trifluoroacetoxy and azido ligands and the optical resolution of 2-iodo-α-methylbenzhydrol, the starting material for the synthesis of 7, are reported.
New hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: Synthesis, structure, and reactivity
Niedermann, Katrin,Welch, Jan M.,Koller, Raffael,Cvengro, Ján,Santschi, Nico,Battaglia, Philip,Togni, Antonio
scheme or table, p. 5753 - 5761 (2010/09/18)
Several new five- and a six-membered heterocyclic monochloroiodanes, including two cationic species, were synthesized. Three of which were used for the preparation of corresponding trifluoromethylation reagents. These compounds were characterized by X-ray crystallography for a comparative structural study. A reactivity study on the trifluoromethylation of para-toluenesulfonic acid has been conducted in order to compare initial rates. Compounds having a longer I-O bond display a higher reactivity.
