18306-68-8Relevant academic research and scientific papers
Phosphorylation of N-trimethylsilyllactams
Uryupin, A. B.,Rakhov, I. A.,Kolesova, V. A.,Petrovskii, P. V.,Mastryukova, T. A.,Kabachnik, M. I.
, p. 1556 - 1560 (2007/10/02)
Treatment of N-trimethylsilyllactams with phosphoryl chlorides results in mixtures of products, whose formation can be explained by competition between N- and O-phosphorylation. - Key words: N-trimethylsilyllactams, dual reactivity; N-phosphoryllactams, synthesis.
REACTIONS OF PHOSPHITES WITH TRICHLOROACETONITRILE
Kutyrev, A. A.,Moskva, V. V.,Alparova, M. V.
, p. 1332 - 1336 (2007/10/02)
Dialkyl hydrogen, sodium dialkyl, and dialkyl silyl phosphites react with trichloroacetonitrile by the Atherton-Todd scheme.Trialkyl phosphites add at the C(*)N bond of trichloroacetonitrile with the formation of trialkyl phosphorimidates.
