183322-93-2Relevant academic research and scientific papers
Highly enantioselective synthesis of multifunctionalized allylic building blocks via oxazaborolidine-catalyzed borane reduction
Byung, Tae Cho,Sung, Hye Shin
, p. 6959 - 6966 (2007/10/03)
A simple and convenient synthesis of optically active alkenyl β-hydroxy sulfides with high enantiomeric excess by CBS-oxazaborolidine- catalyzed borane reduction of the corresponding β-keto sulfides and its application to synthesis of chiral alkenic diols have been established.
Asymmetric synthesis of chiral vinylic epoxides and α-hydroxy-β,γ- unsaturated esters via (-)-menthol based auxiliary and enzymatic resolution respectively
Vankar,Bhattacharya,Vankar
, p. 1683 - 1694 (2007/10/03)
Using (-)-menthol as an auxiliary, three chiral vinylic epoxides have been synthesised from the corresponding glycidic esters via α-hydroxy-β,γ- unsaturated esters. Enzymatic resolution of α-acetoxy-β,γ-unsaturated esters using PLAP leads to optically active α-hydroxy-β,γ-unsaturated esters.
Asymmetric epoxidation of chiral allylic alcohols
Warmerdam, Erwin G.J.C.,Van Den Nieuwendijk, Adrianus M.C.H.,Brussee, Johannes,Kruse, Chris G.,Van Der Gen, Arne
, p. 2539 - 2550 (2007/10/03)
Two series of chiral allylic alcohols, derived from α,β-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate syst
