183322-93-2Relevant academic research and scientific papers
Highly enantioselective synthesis of multifunctionalized allylic building blocks via oxazaborolidine-catalyzed borane reduction
Byung, Tae Cho,Sung, Hye Shin
, p. 6959 - 6966 (2007/10/03)
A simple and convenient synthesis of optically active alkenyl β-hydroxy sulfides with high enantiomeric excess by CBS-oxazaborolidine- catalyzed borane reduction of the corresponding β-keto sulfides and its application to synthesis of chiral alkenic diols have been established.
Asymmetric epoxidation of chiral allylic alcohols
Warmerdam, Erwin G.J.C.,Van Den Nieuwendijk, Adrianus M.C.H.,Brussee, Johannes,Kruse, Chris G.,Van Der Gen, Arne
, p. 2539 - 2550 (2007/10/03)
Two series of chiral allylic alcohols, derived from α,β-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate syst
Asymmetric synthesis of chiral vinylic epoxides and α-hydroxy-β,γ- unsaturated esters via (-)-menthol based auxiliary and enzymatic resolution respectively
Vankar,Bhattacharya,Vankar
, p. 1683 - 1694 (2007/10/03)
Using (-)-menthol as an auxiliary, three chiral vinylic epoxides have been synthesised from the corresponding glycidic esters via α-hydroxy-β,γ- unsaturated esters. Enzymatic resolution of α-acetoxy-β,γ-unsaturated esters using PLAP leads to optically active α-hydroxy-β,γ-unsaturated esters.
