183367-63-7Relevant articles and documents
Reversible generation of glycosyl radicals from telluroglycosides under photochemical and thermal conditions
Yamago, Shigeru,Miyazoe, Hiroshi,Yoshida, Jun-ichi
, p. 2339 - 2342 (1999)
1-β-Telluroglycosides isomerize to α-isomers upon photolysis and thermolysis. The isomerization follows first-order reaction kinetics and proceeds through a glycosyl radical intermediate by homolytic C-Te bond cleavage. The radicals so generated are trapp
O-glycosidation of telluroglycoside by electrochemical oxidation
Yamago, Shigeru,Kokubo, Koji,Yoshida, Jun-Ichi
, p. 111 - 112 (2007/10/03)
The electrochemical oxidation of telluroglycosides in the presence of primary or secondary alcohols results the O-glycosidation with high efficiency. Difference of the oxidation potential is nicely accounted for that of the reactivity of armed-and disarmed-telluroglycosides.