18338-27-7

Basic information

• Product Name: Silanethiol, trimethyl-
• Synonyms: trimethyl-silanethiol;Silanethiol,trimethyl;trimethylsilylthiol;Trimethyl-silanthiol
• CAS NO: 18338-27-7
• Molecular Formula: C3H10SSi
• Molecular Weight: 106.264
• Mol File: 18338-27-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 77-80 °C
• Density: 0.831±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Silanethiol, trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanethiol, trimethyl-(18338-27-7)
• EPA Substance Registry System: Silanethiol, trimethyl-(18338-27-7)

Safety Data

• Hazardous Substances Data: 18338-27-7(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 94089-90-4 phosphan 
• 76275-42-8 O-trimethylsilyl 1,3,3-trimethylbicyclo<2.2.1>heptane-2-thiocarboxylate 
• 41866-81-3 trimethylsiloxide anion 
• 556-61-6 methyl thioisocyanate 
• 75-77-4 chloro-trimethyl-silane 
• 101402-29-3 N-<(trimethylsilyl)methyl>thiobenzamide 
• 624-49-7 dimethylfumarate 
• 463-58-1 carbon oxide sulfide 
• 92231-05-5 hexamethyldisilazide 
• 115526-35-7 2,4-dimercapto-2,4-dithioxo-1,3-bis(trimethylsilyl)-1,3-diaza-2λ⁵,4λ⁵-diphosphetidine 

Downstream Products

• 95665-02-4 F₃SiSH 
• 7783-61-1 silicon tetrafluoride 

Relevant articles and documents

Unprecedented 1,4-stannatropy: Effective generation of azomethine ylides as nitrile ylide equivalents from N-(stannylmethyl)thioamides

Generation and cycloaddition of less- or non-stabilized azomethine ylides, or nitrile ylide equivalents, via unprecedented 1,4-stannatropy of N-(tributylstannylmethyl)thioamides were achieved. The reactions with dipolarophiles, such as electron-deficient alkenes and alkynes, afforded corresponding pyrrolidine and pyrrole derivatives effectively. The Royal Society of Chemistry 2006.

Gas- Phase Ion Chemistry of Siloxide and Silamide Ions by Using the Flowing Afterglow. Unusual Rearrangements Involving SiO and SiS Bond Formation

Siloxide ions undergo O/S exchange reactions with suitable sulfur-containing neutrals, e.g.H3SiO- + CS2 -> H3SiS- + COS.Silamide ions similarly undergo NR/O and NR/S exchange reactions together with nucleophilic displacement reactions, e.g.: .No simple correlation between rate and mechanism is observed for all the studied reactions.

Gas-phase Thermolyses. Part 3. Gas-phase Thermolysis of Silylated Thionocarboxylic Acid Derivatives: a Route to Thioketens?

The unimolecular gas-phase thermolytic decomposition of three silylated thionocarboxylic acid derivatives (2b), (3), and (8) have been studied by the flash vacuum thermolysis-field ionization mass spectrometry technique in the temperature range from 783 to 1404 K in order to elucidate its possible applicability as a route to thioketens.Only very minor amounts of the expected thioketens were found, whereas the corresponding ketens were obtained as the major products.A possible mechanism for keten formation is discussed.