183581-92-2Relevant academic research and scientific papers
Bromination of dimethyl I-substituted indole-2,3-dicarboxylates
Miki, Yasuyoshi,Umemoto, Misako,Nakamura, Mai,Hibino, Hajime,Ohkita, Noriko,Kato, Akiko,Aoki, Yoshiyuki
, p. 1893 - 1899 (2007/10/03)
Treatment of dimethyl indole-2,3-dicarboxylate with pyridinium hydrobromide perbromide or bromine in the presence of Lewis acid gave dimethyl 5-bromoindole-2,3-dicarboxylate as the sole product. In a similar manner, dimethyl 1-benzyl- and 1-benzenesulfony
Magnesiation of indoles with magnesium amide bases
Kondo, Yoshinori,Yoshida, Akihiro,Sakamoto, Takao
, p. 2331 - 2332 (2007/10/03)
1-Substituted indole derivatives are deprotonated with Hauser bases (R2NMgBr) or magnesium diamide [(R2N)2-Mg] to give magnesioindoles which are then reacted with electrophiles.
