18402-22-7 Usage
General Description
N-Tetradecyltrichlorosilane is a chemical compound with the molecular formula C14H31Cl3Si. It is a silane compound that is commonly used as a surface modifying agent in various industrial applications. N-Tetradecyltrichlorosilane is known for its ability to effectively modify the surface properties of materials, particularly in enhancing their hydrophobic and oleophobic characteristics. This makes it useful in coatings, adhesives, and sealants, as well as in the production of various types of polymers and composites. Additionally, it is also used in the manufacturing of optical films, electronic materials, and in other areas where surface modification is necessary. However, it is important to handle N-Tetradecyltrichlorosilane with caution, as it is a highly reactive compound that requires proper handling and storage procedures to prevent any potential hazards.
Check Digit Verification of cas no
The CAS Registry Mumber 18402-22-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,4,0 and 2 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 18402-22:
(7*1)+(6*8)+(5*4)+(4*0)+(3*2)+(2*2)+(1*2)=87
87 % 10 = 7
So 18402-22-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H29Cl3Si/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-18(15,16)17/h2-14H2,1H3
18402-22-7Relevant articles and documents
Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization
Hanna, Steven,Butcher, Trevor W.,Hartwig, John F.
supporting information, p. 7129 - 7133 (2019/09/12)
We report a contra-thermodynamic isomerization of internal olefins to terminal olefins driven by redox reactions and formation of Si-F bonds. This process involves chain-walking hydrosilylation of internal olefins and subsequent formal retro-hydrosilylation. The process rests upon the high activities of platinum hydrosilylation catalysts for isomerization of metal alkyl intermediates and a new, metal-free process for the conversion of alkylsilanes to alkenes. By this approach, 1,2-disubstituted and trisubstituted olefins are converted to terminal olefins.
