18406-91-2

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 499-94-5 (S)-carvomenthene 
• 17873-21-1 trichloro-((S)-p-menth-1-en-7-yl)-silane 
• 676-58-4 methylmagnesium chloride 
• 18172-67-3 beta-pinene 

Relevant academic research and scientific papers

Synthesis of β,γ-Unsaturated Phenyl Esters by Aluminium Chloride Initiated Reactions of Allylsilanes with Aryl Chloroformates

Phenyl chloroformate (1) reacts with the allylsilanes 2a-h in the presence of aluminium chloride to give the β,γ-unsaturated phenyl esters 3a-h in 50-90percent yield.While these reactions proceed in the usual manner with allylic inversion, (1,1-dimethylal

SYNTHESE D'ALLYLSTANNATES ET D'ALLYLSILANES EN SERIE TERPENIQUE

Allylstannates and allylsilanes of the terpenic series have been easily obtained from the corresponding hydrocarbons by metallation with n-butyllithium-tetramethylethylene diamine complex, followed by quenching with trimethylstannyl or trimethylsilyl chloride.