18435-37-5

Basic information

• Product Name: 3-methylundec-1-ene
• Synonyms: 1-undecene, 3-methyl-; 3-methyl-1-undecene
• CAS NO: 18435-37-5
• Molecular Formula: C₁₂H₂₄
• Molecular Weight: 168.319
• Mol File: 18435-37-5.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 205°C at 760 mmHg
• Flash Point: 91.1°C
• Density: 0.757g/cm³
• Vapor Pressure: 0.366mmHg at 25°C
• Refractive Index: 1.429
• CAS DataBase Reference: 3-methylundec-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methylundec-1-ene(18435-37-5)
• EPA Substance Registry System: 3-methylundec-1-ene(18435-37-5)

Safety Data

• Hazardous Substances Data: 18435-37-5(Hazardous Substances Data)

Upstream product

• 111-85-3 n-chlorooctane 
• 3536-96-7 vinylmagnesium chloride 
• 38972-70-2 (E)-3-methylundec-2-en-1-ol 
• 112-41-4 1-dodecene 
• 111-83-1 1-bromo-octane 
• 5732-02-5 3-methylene-1-undecene 

Relevant articles and documents

Convenient Synthesis of Diene-Zirconocenes and Regioselective Partial Reduction of the More Highly Substituted Double Bonds of Conjugated Dienes via Complexation with Zirconocenes and Protonolysis

Conjugated dienes can be initially converted to their zirconocene complexes most conveniently by their reaction with (C5H5)2ZrCl2 and freshly ground Mg; the resultant complexes can then be protonolysed with 3 mol dm-3 HCl to give regioselectively monoenes corresponding to partial hydrogenation of the more highly substituted double bond.

Ni-catalyzed alkylative dimerization of vinyl Grignard reagents using alkyl fluorides

Alkyl halides underwent unique cross-coupling reaction with vinylmagnesium chloride in the presence of Ni catalyst to give 2-alkyl-3-butenyl Grignard reagent (1) in high yields. This reaction proceeded efficiently at 25 °C in THF using primary and seconda