Journal of the Chemical Society. Chemical communications p. 1830 - 1831 (1993)
Update date:2022-08-30
Topics:
Maye, John P.
Negishi, Ei-ichi
Conjugated dienes can be initially converted to their zirconocene complexes most conveniently by their reaction with (C5H5)2ZrCl2 and freshly ground Mg; the resultant complexes can then be protonolysed with 3 mol dm-3 HCl to give regioselectively monoenes corresponding to partial hydrogenation of the more highly substituted double bond.
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