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Benzene, [(3E)-4-iodo-3-butenyl]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

184370-59-0

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184370-59-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 184370-59-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,4,3,7 and 0 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 184370-59:
(8*1)+(7*8)+(6*4)+(5*3)+(4*7)+(3*0)+(2*5)+(1*9)=150
150 % 10 = 0
So 184370-59-0 is a valid CAS Registry Number.

184370-59-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name (E)-1-iodo-4-phenyl-1-butene

1.2 Other means of identification

Product number -
Other names (E)-1-Iodo-4-phenyl-1-butene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:184370-59-0 SDS

184370-59-0Relevant articles and documents

Direct Access to α,β-Unsaturated Ketones via Rh/MgCl2-Mediated Acylation of Vinylsilanes

Chen, Zi-Yan,Deng, Xue-Zu,Song, Yang,Xue, Fei,Yamane, Motoki,Yue, Yan-Ni

, p. 12693 - 12704 (2021/09/28)

We report herein the facile and practical construction of α,β-unsaturated ketones via rhodium-catalyzed direct acylation of vinylsilanes with readily available and abundant carboxylic acids. This protocol features access to a diverse array of synthetically useful functionalities with moderate to excellent yields. More importantly, the late-stage functionalization of pharmaceuticals was also realized with synthetically useful yield.

A Copper(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl-Substituted Alkenes: Synthesis of Enantioenriched γ,γ-gem-Difluoroallylboronates

Kojima, Ryoto,Akiyama, Sota,Ito, Hajime

supporting information, p. 7196 - 7199 (2018/06/15)

The first catalytic enantioselective γ-boryl substitution of CF3-substituted alkenes is reported. A series of CF3-substituted alkenes was treated with a diboron reagent in the presence of a copper(I)/Josiphos catalyst to afford the c

Stereodivergent Olefination of Enantioenriched Boronic Esters

Armstrong, Roly J.,García-Ruiz, Cristina,Myers, Eddie L.,Aggarwal, Varinder K.

supporting information, p. 786 - 790 (2017/01/14)

A stereodivergent coupling reaction between vinyl halides and boronic esters is described. This coupling process proceeds without a transition-metal catalyst, instead proceeding by electrophilic selenation or iodination of a vinyl boronate complex followed by stereospecific syn or anti elimination. Chiral, nonracemic boronic esters could be coupled with complete enantiospecificity. The process enables the highly stereoselective synthesis of either the E or Z alkene from a single isomer of a vinyl coupling partner.

An expeditious and atom-economical synthesis of a new generation of substituted [4.6.4.6]fenestradienes

Charpenay, Melanie,Boudhar, Aicha,Blond, Gaelle,Suffert, Jean

supporting information; experimental part, p. 4379 - 4382 (2012/06/29)

With finesse and strain: Highly strained derivatives of fenestranes, [4.6.4.6]fenestradienes, have been prepared using a remarkable reaction cascade featuring a 4-exo-dig cyclocarbopalladation, a Sonogashira-type coupling, a regioselective alkynylation, and an 8π/6π electrocyclization sequence. Copyright

Palladium-catalyzed direct functionalization of benzoxazoles with alkenyl iodides

Gerelle, Maria,Dalencon, Anne J.,Willis, Michael C.

supporting information; experimental part, p. 1954 - 1957 (2012/05/07)

A straightforward procedure for the palladium-catalyzed direct functionalization of benzoxazoles with alkenyl iodides is described. The reactions employ a Pd(II)-precatalyst and use 'on water' conditions to achieve the ready union of a range of di- and tr

Iododesilylation of TIPS-, TBDPS-, and TBS-substituted alkenes in connection with the synthesis of amphidinolides B/D

Sidera, Mireia,Costa, Anna M.,Vilarrasa, Jaume

, p. 4934 - 4937 (2011/11/29)

The C-Si bonds of triisopropylsilyl-substituted alkenes, 1,3-dienes, and related multifunctional substrates, as well as analogous C-TBDPS and C-TBS bonds, are readily and chemoselectively cleaved with NIS (or other sources of I+, such as N-iodo

Catalytic enantioselective conjugate allylation of unsaturated methylidene ketones

Brozek, Laura A.,Sieber, Joshua D.,Morken, James P.

supporting information; scheme or table, p. 995 - 997 (2011/05/15)

The use of unsaturated methylidene ketones in catalytic conjugate allylations allows a significant expansion in substrate scope and, with appropriate chiral ligands, occurs in a highly enantioselective fashion.(Figure Presented)

Synthesis of aminocyclobutanes through ring expansion of N-vinyl-β-lactams

Cheung, Lawrence L. W.,Yudin, Andrei K.

supporting information; body text, p. 1281 - 1284 (2009/08/12)

Both eight-membered enamide rings and fused [4.2.0]aminocyclobutane- containing δ-lactams can be accessed from N-vinyl-β-lactams. The eight-membered rings are made through a [3,3] sigmatropic rearrangement. At elevated temperature, the eight-membered lact

A practical transformation of aldehydes into (E)-iodoalkenes with geminal dichromium reagents

Takai, Kazuhiko,Ichiguchi, Tetsuya,Hikasa, Shintaro

, p. 1268 - 1270 (2007/10/03)

A catalytic cycle of a chromium salt in a stereoselective transformation of aldehydes to (E)-l-iodoalkenes using a geminal dichromium reagent, is assembled with zinc, Me3SiCl, and NaI in dioxane.

Palladium-catalysed hydrostannylations of 1-bromoalkynes. A practical synthesis of (E)-1-stannylalk-1-enes

Boden, Christopher D. J.,Pattenden, Gerald,Ye, Tao

, p. 2417 - 2419 (2007/10/03)

A practical synthesis of (E)-1-stannylalk-1-enes containing a range of oxygen and nitrogen functionality is highlighted, involving hydrostannylation followed by palladium-catalysed carbon-bromine bond cleavage reactions of 1-bromoalkynes.

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