18448-19-6Relevant academic research and scientific papers
A new approach to the synthesis of trifluoromethylated products of the -sigmatropic rearrangement
Andreev, V. G.
, p. 1209 - 1213 (1994)
CH-acids of general formula CF3CH(X)CF3 (X = CF3, CO2R) react with 2,3-unsaturated alcohols in the presence of bases to give trifluoromethylated products of the -sigmatropic rearrangement.These reactions provide a convenient method for the synthesis of 2-alkenyl-2-trifluoromethylmalonates. - Key words: CH-acids, fluorinated; -sigmatropic rearrangement; 2-alkenyl-2-trifluoromethylmalonates.
