Russian Chemical Bulletin p. 1209 - 1213 (1994)
Update date:2022-07-30
Topics:
Andreev, V. G.
CH-acids of general formula CF3CH(X)CF3 (X = CF3, CO2R) react with 2,3-unsaturated alcohols in the presence of bases to give trifluoromethylated products of the <3,3>-sigmatropic rearrangement.These reactions provide a convenient method for the synthesis of 2-alkenyl-2-trifluoromethylmalonates. - Key words: CH-acids, fluorinated; <3,3>-sigmatropic rearrangement; 2-alkenyl-2-trifluoromethylmalonates.
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