1845-30-3

Basic information

• Product Name: cis-VERBENOL
• Synonyms: CIS-VERBENOL;trans-4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-ol;(1R,2R,5R)-4,7,7-trimethylbicyclo[3.1.1]hept-3-en-2-ol;cis-4,6,6-trimethy Ibicyclo [3.1.1] hept-3-en-2-01
• CAS NO: 1845-30-3
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.235
• Mol File: 1845-30-3.mol
• Article Data: 56

Chemical Properties

• Melting Point: 15.5°C
• Boiling Point: 234.73°C (rough estimate)
• Appearance: /
• Density: 0.9684
• Refractive Index: 1.4912 (estimate)
• PKA: 14.56±0.60(Predicted)
• CAS DataBase Reference: cis-VERBENOL(CAS DataBase Reference)
• NIST Chemistry Reference: cis-VERBENOL(1845-30-3)
• EPA Substance Registry System: cis-VERBENOL(1845-30-3)

Safety Data

• Hazardous Substances Data: 1845-30-3(Hazardous Substances Data)

Usage

General Description

Cis-verbenol is a natural organic compound that is found in the essential oil of various plants, including cypress and pine. It is classified as a terpene alcohol and is known for its pleasant, woody, and slightly floral odor. Cis-verbenol is commonly used in the fragrance industry as a scent enhancer, and it is also of interest to the agricultural industry, as it serves as a pheromone precursor for certain bark beetle species. Additionally, it has been shown to possess antifungal and antibacterial properties, making it a potential candidate for use in natural pesticides and antimicrobial products.

Upstream product

• 80-56-8 Pinene 
• 7785-26-4 (-)-α-pinene 
• 18881-04-4 (S)-cis-Verbenol 
• 80-57-9 (-)-Verbenone 
• 80-56-8 rac-α-pinene 
• 7785-70-8 (+)-α-pinene 
• 98-83-9 isopropenylbenzene 
• 7722-84-1 dihydrogen peroxide 
• 67-64-1 acetone 
• 18309-32-5 Verbenone 
• 1203-21-0 trans-verbenyl acetate 
• 473-06-3 chrysanthenone 
• 80-57-9 (+/-)-2,6,6-trimethylbicyclo[3.1.1]hept-2-en-4-one 
• 80-57-9 verbenone 

Downstream Products

• 109841-86-3 benzyl-((1S,4R)-pin-2-en-4-yl)-ether 
• 4080-46-0 2⁽¹⁰⁾,3-pinadiene 
• 99-87-6 4-methylisopropylbenzene 
• 122621-69-6 <1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene 
• 80-57-9 verbenone 
• 22571-78-4 (+)-cis-pinononoic acid 
• 288848-24-8 (1S,3R)-3-acetyl-2,2-dimethylcyclobutane carboxylic acid 
• 916595-90-9 (2R,3S,4S,5R,6R)-2-Hydroxymethyl-6-(4,6,6-trimethyl-bicyclo[3.1.1]hept-3-en-2-yloxy)-tetrahydro-pyran-3,4,5-triol 
• 1307886-98-1 (1S,2S,6R)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol 
• 1361947-93-4 (1S,5R,6S)-6-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl nicotinate 
• 1361947-97-8 (1S,2S,6R)-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-ene-1,2-diyl dinicotinate 
• 66885-03-8 (+)-cis-verbenol epoxide 
• 18309-32-5 Verbenone 
• 924265-29-2 (+)-verbenone epoxide 

Relevant articles and documents

Individual stereoisomers of verbenol and verbenone express bioactive features

Naturally occurring terpene core compounds have been used extensively in both pharmaceutical and cosmetic industry. However, since chirality of these compounds has profound influence on the level of their bioactivity, the aim of the present study was to a

Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst

Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction.

Oxy-functionalization of olefins with neat and heterogenized binuclear V(IV)O and Fe(II)complexes: Effect of steric hindrance on product selectivity and output in homogeneous and heterogeneous phase

Neat {[VO(sal2bz)]2; [Fe(sal2bz)(H2O)2]2·2H2O} and zeolite-Y immobilized {[VO(sal2bz)]2-Y; [Fe(sal2bz)(H2O)2]2-Y} binuclear complexes have been prepared and characterized by spectroscopic techniques (IR, UV–vis), elemental analyses (CHN, ICP-OES), thermal study (TGA), scanning electron micrograph (SEM), adsorption study (BET)and X-ray diffraction (XRD)patterns. Neat (homogeneous)and immobilized (heterogeneous)complexes were employed as catalysts in the oxidation of olefins, namely, cyclohexene, limonene and α-pinene in the presence of 30% hydrogen peroxide. 100% conversion of cyclohexene and α-pinene was obtained while limonene was oxidized up to 90%. Homogeneous catalysts showed highly selective result as neat [VO(sal2bz)]2 complex has provided 87% cyclohexane-1,2-diol and neat [Fe(sal2bz)(H2O)2]2·2H2O complex has provided 79% verbenone in oxidation of cyclohexene and α-pinene, respectively. We have observed that due to steric hindrance, formation of olefinic oxidation products increases on moving from α-pinene to limonene and limonene to cyclohexene. Additionally. recovered heterogeneous catalysts showed intact results up to two consecutive runs. Probable catalytic mechanism has been proposed for oxidation of cyclohexene.