18467-14-6

Basic information

• Product Name: Benzenamine, N-[(3-bromophenyl)methylene]-
• CAS NO: 18467-14-6
• Molecular Formula: C13H10BrN
• Molecular Weight: 260.133
• Mol File: 18467-14-6.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[(3-bromophenyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[(3-bromophenyl)methylene]-(18467-14-6)
• EPA Substance Registry System: Benzenamine, N-[(3-bromophenyl)methylene]-(18467-14-6)

Safety Data

• Hazardous Substances Data: 18467-14-6(Hazardous Substances Data)

Usage

General Description

Benzenamine, N-[(3-bromophenyl)methylene]- is a chemical compound with the molecular formula C13H10BrN. It is a yellow to orange powder that is primarily used as an intermediate in the production of various dyes and pigments. Benzenamine, N-[(3-bromophenyl)methylene]- is also used in the synthesis of pharmaceuticals and agrochemicals. It is important to handle this chemical with care, as it is considered to be hazardous if ingested or inhaled, and can cause skin and eye irritation. Proper safety precautions should be taken when working with this chemical, including the use of protective equipment and adherence to safe handling procedures.

Upstream product

• 3132-99-8 m-bromobenzoic aldehyde 
• 62-53-3 aniline 
• 15852-73-0 (3-Bromophenyl)methanol 

Downstream Products

• 62305-56-0 [(3-Bromo-phenyl)-phenylamino-methyl]-phosphinic acid; compound with phenylamine 
• 1159387-04-8 C₁₁H₁₁BrO 
• 1159386-76-1 N-(1-(3-bromophenyl)-2-methylenebut-3-en-1-yl)phenylamine 
• 1228923-35-0 (S)-5-[(R)-(3-bromophenyl)(phenylamino)methyl]furan-2(5H)-one 
• 864377-31-1 2-(3-bromophenyl)-4,6-diphenyl-[1,3,5]triazine 
• 1345202-08-5 9-[3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]-9'-phenyl-2,3'-bi-9H-carbazole 
• 1394138-02-3 C₃₁H₂₇BrN₂O₂ 
• 1394137-91-7 C₂₄H₂₃BrN₂O 
• 1442652-09-6 2-(3-bromophenyl)-1,3,5-triphenyl-1H-pyrrole 
• 1442652-00-7 2,5-bis(3-bromophenyl)-1,3-diphenyl-1H-pyrrole 
• 1449678-28-7 C₁₇H₁₆BrNO 
• 5438-81-3 3,3-dimethyl-1,4-diphenyl-azetidin-2-one 
• 675826-91-2 2-(3-bromophenyl)-4-phenylquinoline 
• 251966-53-7 N-(3-bromobenzyl)benzenamine 

Relevant articles and documents

Method for synthesizing aluminum phosphate molecular sieve catalytic imine

The invention discloses a method for catalyzing synthesis of an imine by using an aluminum phosphate molecular sieve, and belongs to the technical field of catalytic synthesis of imines. Under the action of an HP-MeAlPO-5 molecular sieve, air or oxygen is used as an oxidant, and an amine and an alcohol which contain different substituents are directly subjected to oxidative coupling to synthesizethe imine under mild conditions. According to the method provided by the invention, the reaction conditions of the adopted catalytic system are mild, and the TOF is high; a reaction can efficiently catalyze the synthesis of the imine at room temperature under air; and the method can adopt transition metals, which are cheap and easy to obtain, such as iron, cobalt and nickel as a molecular sieve dopant, and the availability of the molecular sieve is improved.

Retraction: Harnessing Thiol as a Benzyl Reagent for Photocatalytic Reductive Benzylation of Imines (Organic Letters DOI: 10.1021/2Facs.orglett.0c00065)

The authors retract this article after finding in subsequent studies that the quality of the purchased catalysts has a notable impact on the reproducibility of the results. Accordingly, the authors note that additional work is necessary to understand the

Photoredox Radical/Polar Crossover Enables Construction of Saturated Nitrogen Heterocycles

Photoredox-mediated radical/polar crossover (RPC) processes offer new avenues for the synthesis of cyclic molecules. This process has been realized for the construction of medium-sized saturated nitrogen heterocycles. Photocatalytically generated alkyl ra