1847-82-1Relevant academic research and scientific papers
REACTION OF ORGANIC CARBONATES WITH AMINES I. REACTION OF ALKYL PHENYL CARBONATES WITH PRIMARY ALIPHATIC AMINES
Mikheev, V. V.,Svetlakov, N. V.,Garipov, R. M.
, p. 215 - 220 (2007/10/02)
The reaction of alkyl phenyl carbonates with primary aliphatic amines, leading to the formation of N-alkylurethanes, was investigated.The reaction has overall third order, which is explained by the catalytic action of the amine.The effect of the structure of the alkyl radical and the character of the substituent in the phenyl group of the alkyl phenyl carbonates and also the effect of the polarity of the solvent on the rate of the transformation were investigated.The reaction obeys the Hammett equation.
