29430-39-5

Usage

Uses

Used in Pharmaceutical Industry:
3-Methylphenyl chloroformate is used as a key intermediate in the synthesis of various pharmaceutical compounds for its ability to facilitate the formation of carbamates, which are essential in the development of drugs with diverse therapeutic applications.
Used in Agrochemical Industry:
In the agrochemical sector, 3-Methylphenyl chloroformate is utilized as a reagent in the production of pesticides and other crop protection agents, contributing to the creation of effective and targeted pest control solutions.
Used in Advanced Materials Industry:
3-Methylphenyl chloroformate is employed as a precursor in the development of advanced materials, such as polymers and coatings, due to its reactive nature and capacity to form stable linkages within complex molecular structures.

InChI:InChI=1/C8H7ClO2/c1-6-3-2-4-7(5-6)11-8(9)10/h2-5H,1H3

Upstream product

• 75-44-5 phosgene 
• 108-39-4 3-methyl-phenol 
• 32315-10-9 bis(trichloromethyl) carbonate 

Downstream Products

• 107415-86-1 4-hydroxy-piperidine-1-carboxylic acid m-tolyl ester 
• 22719-82-0 ethyl (m-tolyl)carbonate 
• 42571-16-4 C₁₇H₁₇ClN₂O₂ 
• 68621-57-8 Methyl-(3-nitro-phenyl)-carbamic acid m-tolyl ester 
• 38235-04-0 m-Tolyloxycarbonyldimethyldithiocarbamat 
• 38235-05-1 m-Tolyloxycarbonyldiethyldithiocarbamat 
• 38235-03-9 m-Tolyloxycarbonylmethyldithiocarbamat 
• 58610-10-9 thiocarbonic acid S-(4-phenyl-5-thioxo-4,5-dihydro-[1,3,4]thiadiazol-2-yl) ester O-m-tolyl ester 
• 58610-02-9 thiocarbonic acid S-(5-oxo-4-phenyl-4,5-dihydro-[1,3,4]thiadiazol-2-yl) ester O-m-tolyl ester 
• 713-94-0 3-Trichloromethylphenyl chloroformate 
• 83498-81-1 N-Isopropyl-carbaminsaeure-m-tolylester 
• 164297-04-5 C₁₈H₁₈N₂O₄S 
• 78258-80-7 4-methyl-3H-benzooxazol-2-one 
• 22876-16-0 6-methylbenzoxazolin-2-one 

Relevant academic research and scientific papers

Versatile Cp*Co(III)(LX) Catalyst System for Selective Intramolecular C-H Amidation Reactions

Herein, we report the development of a tailored cobalt catalyst system of Cp*Co(III)(LX) toward intramolecular C-H nitrene insertion of azidoformates to afford cyclic carbamates. The cobalt complexes were easy to prepare and bench-stable, thus offering a convenient reaction protocol. The catalytic reactivity was significantly improved by the electronic tuning of the bidentate LX ligands, and the observed regioselectivity was rationalized by the conformational analysis and DFT calculations of the transition states. The superior performance of the newly developed cobalt catalyst system could be broadly applied to both C(sp2)-H and C(sp3)-H carbamation reactions under mild conditions.

Visible-Light-Induced Intramolecular C(sp2)-H Amination and Aziridination of Azidoformates via a Triplet Nitrene Pathway

Catalytic intramolecular C-H amination and aziridination reactions of o-allylphenyl azidoformates have been achieved under visible-light irradiation, providing a mild, clean, and efficient method for the synthesis of useful benzoxazolones and [5.1.0] bicyclic aziridines. Mechanistic studies suggest that a triplet nitrene acts as the reactive intermediate. The chemoselectivity of the reaction, with alkyl olefin aziridination ? electron deficient olefin aziridination ≈ C(sp2)-H amination ? C(sp3)-H amination was observed, which may be instructive in the development of an understanding of visible-light-induced triplet nitrene transformation reactions.

Preparation of chloroformates using bis(trichloromethyl)carbonate

The synthesis of eight chloroformates using bis(trichloromethyl) carbonate(BTC) is reported. It has been found that the yields by this BTC method are improved over the earlier phosgene method, and sodium hydroxide is better than pyridine as catalyst for the preparation of phenyl chloroformate.

Heat-sensitive recording materials and phenol compounds

Heat-sensitive recording materials contain an electron-donating chromogenic compound and an electron-attracting compound. The recording materials also contain at least one compound represented by the following formula: STR1 wherein R1 and R3 mean a hydrogen atom or an alkyl, aralkyl or aryl group, R2 and R4 denote an alkyl, alkenyl, aralkyl or aryl group, X1, X2, Y1 and Y2 stand for an oxygen or a sulfur atom, and --Z1 -- and --Z2 -- are a specific aromatic group. Also provided are phenol compounds represented by the following formula: STR2 wherein R1, R2, X1 and Y1 have the same meanings as defined above; R5 and R6 are a hydrogen or halogen atom or an alkyl, alkoxy, aralkyl, aryl or hydroxyl group; p and q stand for an integer of 1-4; R5 and R6 may be either the same or different when p and q represent an integer of 2 or greater; and --Z3 -- means a specific divalent group.