18476-57-8Relevant academic research and scientific papers
REACTIONS OF ?-ALLYL COMPLEXES OF Ti(III) WITH ALLYL, ALKYL, AND PROPARGYL ELECTROPHILES
Kasatkin, A. N.,Kulak, A. N.,Tolstikov, G. A.,Lomakina, S. I.
, p. 1875 - 1889 (2007/10/02)
The reactions of the ?-allyl complexes of Ti(III) with allyl bromides lead to the production of a mixture of cross-coupling and homocoupling products.In the case of alkyl and propargyl halides the dehalogenation products are formed.The reaction of the ?-allyl complexes of Ti(III) with allyl acetates, allyl phenyl ethers, and allyl aryl sulfones are catalyzed by Pd(PPh3)4 and give cross-coupling or elimination products, depending on the structure of the initial substrate.
