18537-69-4Relevant articles and documents
SPECTRAL INVESTIGATION OF GEOMETRIC ISOMERISM IN DIMERIC ISOBUTYLENE NITROSOCHLORIDE
Mironovskaya, N. M.,Vasil'ev, A. F.,Margolin, L. N.,Nazarova, E. B.,Razinkova, L. N.,Chimishkyan, A. L.
, p. 1761 - 1765 (2007/10/02)
The vibrational spectra of the geometric isomers of dimeric isobutylene nitrosochloride in the solid form and in the solution were obtained and analyzed.In solution the cis isomer changes rapidly into the trans form.Polar solvents retard the isomerization somewhat, stabilizing the cis isomer.The kinetics of the cis-trans isomerization of dimeric isobutylene nitrosochloride in acetonitrile in the range of 10 - 35 deg C were investigated.The rate constants and activation parameters were determined.