18596-46-8Relevant academic research and scientific papers
A C2 Fragment as Four-Electron σ Donor
Petz, Wolfgang,Andrada, Diego M.,Hermann, Markus,Frenking, Gernot,Neumüller, Bernhard
, p. 1096 - 1099 (2017)
The formation and X-ray structure analysis of the PtIV complex [(CH2C{PPh2C6H4}2)PtI2] is reported. The molecule possesses the orthometalated ligand (PPh3)2C→CH2, which serves via its C2 fragment as an unprecedented four-electron σ donor.
