18598-93-1Relevant academic research and scientific papers
THE REACTION OF CARBANIONS WITH 2-SUBSTITUTED -2-NITROPROPANES SUBSTITUTION AND DIMERIZATION OCCURRING BY RADICAL CHAIN PROCESSES INVOLVING ELECTRON TRANSFER
Russell, Glen A.,Mudryk, Boguslaw,Ros, Francisco,Jawdosiuk, Mikolaj
, p. 1059 - 1068 (1982)
The reaction of mono-enolate anions with O2NCMe2X where X=Cl, NO2, p-MePhSO2 yield coupling (RCOCH(R')(CMe2NO2) and enolate dimerization products (RCOCH(R')CH(R')COR) by free radical chain mechanisms involving bimolecular substitution or electron transfer reactions between the enolate anion and the intermediate nitro alkane radical anion (XCMe2NO2(1-)).
Domino processes as a tool for recovering substandard reactions. Synthesis and use of nitroacetic acid esters and amides
Scardovi, Noemi,Casalini, Andrea,Peri, Francesca,Righi, Paolo
, p. 965 - 968 (2007/10/03)
(equation presented) Elusive nitroacetic acid esters and amides were obtained through a halogen exchange reaction of the corresponding bromoacetic acid derivatives with polymer-supported nitrite anion. The process is flawed by a side product catalyzed deg
