18608-92-9

Basic information

• Product Name: 1,2:5,6-DI-O-CYCLOHEXYLIDENE-BETA-D-FRUCTOFURANOSE
• Synonyms: 1,2:5,6-DI-O-CYCLOHEXYLIDENE-BETA-D-FRUCTOFURANOSE
• CAS NO: 18608-92-9
• Molecular Formula: C18H28 O6
• Molecular Weight: 0
• Mol File: 18608-92-9.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2:5,6-DI-O-CYCLOHEXYLIDENE-BETA-D-FRUCTOFURANOSE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2:5,6-DI-O-CYCLOHEXYLIDENE-BETA-D-FRUCTOFURANOSE(18608-92-9)
• EPA Substance Registry System: 1,2:5,6-DI-O-CYCLOHEXYLIDENE-BETA-D-FRUCTOFURANOSE(18608-92-9)

Safety Data

• Hazardous Substances Data: 18608-92-9(Hazardous Substances Data)

Usage

Chemical compound

A derivative of fructose, a simple sugar found in many fruits and honey.

Common use

Used in organic chemistry as a protecting group for the hydroxyl groups of fructose during organic synthesis.

Applications

Utilized in the production of various pharmaceuticals and as a reagent in chemical reactions.

Stability

The compound is stable, making it suitable for a variety of applications in organic chemistry.

Melting point

Has a high melting point, which contributes to its stability and usefulness in chemical reactions.

Role

Important for its role in the protection of fructose molecules during chemical reactions.

Synthesis

Used in the synthesis of other organic compounds, showcasing its versatility in organic chemistry.

Upstream product

• 6347-01-9 fructopyranose 
• 108-94-1 cyclohexanone 
• 57-48-7 D-Fructose 
• 7660-25-5 D-fructose 

Relevant articles and documents

Z-, E-Isomers of 1,2:4,5-di-o-cyclohexylidene-β-D-erythro-hexo-2,3-diulopyranose oxime

The syntheses of 1,2:4,5-di-O-cyclohexylidene-β-D-fructopyranose and 1,2:4,5-di-O-cyclohexylidene-β-D-eryrtro-hexo-2,3-diulopyranose were improved. A method for the separation of isomeric oximes of diulose was developed, and their structures were established by 13C NMR spectroscopy. 3-Amino-3-deoxy-1,2:4,5-di-O-cyclohexylidene-β-D-psycopyranose was obtained.

Catalytic asymmetric epoxidation

A compound and method for producing an enantiomerically enriched epoxide from an olefin using a chiral ketone and an oxidizing agent is disclosed.

Structural probing of ketone catalysts for asymmetric epoxidation

A series of chiral ketones derived from carbohydrates were investigated as catalysts for the asymmetric epoxidation. Fructose-derived ketones are found to be efficient catalysts. The studies show that the structural requirements for the ketone catalysts are very stringent and different types of olefins may require ketones with different structural arrangements. The current study allows us to further understand the chiral ketone catalyzed asymmetric epoxidation and provides some insight for the development of new catalysts.