18629-59-9

Basic information

• Product Name: Ethanethioic acid, (phenylthio)-, S-phenyl ester
• CAS NO: 18629-59-9
• Molecular Formula: C14H12OS2
• Molecular Weight: 260.381
• Mol File: 18629-59-9.mol

Chemical Properties

• CAS DataBase Reference: Ethanethioic acid, (phenylthio)-, S-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethioic acid, (phenylthio)-, S-phenyl ester(18629-59-9)
• EPA Substance Registry System: Ethanethioic acid, (phenylthio)-, S-phenyl ester(18629-59-9)

Safety Data

• Hazardous Substances Data: 18629-59-9(Hazardous Substances Data)

Upstream product

• 56377-57-2 α-bromo-S-phenyl thioacetate 
• 108-98-5 thiophenol 
• 111832-37-2 2-(phenylsulfonyl)oxirane 
• 882-33-7 diphenyldisulfane 
• 62762-20-3 1-phenylthio-1-trimethylsilylethene 
• 103-04-8 (phenylthio)acetic acid 
• 24197-65-7 S-phenyl α-chlorothioacetate 
• 930-69-8 sodium thiophenolate 
• 79-04-9 chloroacetyl chloride 

Relevant articles and documents

Electro-initiated oxygenation of alkenylsilanes in the presence of thiophenol

Electrolysis of alkenylsilanes in the presence of thiophenol with bubbling of molecular oxygen gave the corresponding α-phenylthio carbonyl compounds with the consumption of a catalytic amount of electricity. An electro-initiated radical chain mechanism i

Regioselective synthesis of inhibitors of histone acetyl transferase covalently linking spermidine to the S-terminus of coenzyme A and fragments.

The reaction of a bromoacetylthioester BrCH2CO-S-R (R radical in the coenzyme A series) with spermidine (Spd) derivatives is investigated and it is established that the adduct SpdCOCH2-S-R 1 is the product of the reaction.Parallel studies with model compounds show that this is a general reaction of bromoacetylthioesters.The synthesis of analogs of 1 is described and they correspond to inhibitors of the histone acetyltransferase. Key words: spermidine, coenzyme A, cysteamine, β-aletheine, enzyme inhibitors.

Phenylsulphonyloxiranes as Functional Acyl Anion Equivalents in Organic Synthesis

Phenylsulphonyloxiranes can be lithiated with butyllithium α to the phenylsulphonyl group at low temperature.The anions formed are unstable, but sufficiently reactive to allow the isolation of adducts in good yield following treatment with a variety of el

Novel Alumina-catalysed Reactions of Arylthioalkyl Halides and Related Compounds

Arylthioalkyl halides of the type ArS(CH2)nCl (Ar = phenyl or substituted phenyl, n = 1-4) undergo rearrangement on heating with neutral alumina to 1,n-bis(arylthio)alkanes of type ArS(CH2)nSAr in high yield.Similar rearrangements occur with some closely related structural types.The bis(arylthio)alkanes undergo further reaction with alumina at higher temperatures in air giving diaryl disulphides.Bis(o-iodophenylthio)methane eliminates iodine on heating with alumina, producing dibenzodithiepin.Some observations concerning the mechanism are presented.