18641-42-4Relevant articles and documents
Boron-Catalyzed Aromatic C-H Bond Silylation with Hydrosilanes
Ma, Yuanhong,Wang, Baoli,Zhang, Liang,Hou, Zhaomin
, p. 3663 - 3666 (2016)
Metal-free catalytic C-H silylation of a series of aromatic compounds such as N,N-disubstituted anilines with various hydrosilanes has been achieved for the first time using commercially available B(C6F5)3 as a catalyst. This protocol features simple and neutral reaction conditions, high regioselectivity, wide substrate scope (up to 40 examples), Si-Cl bond compatibility, and no requirement for a hydrogen acceptor.