18642-94-9Relevant articles and documents
An efficient method for synthesizing monofunctionalized derivatives of 1,1,3,3-tetramethyldisiloxane in ionic liquids as recoverable solvents for rhodium catalyst
Kukawka,Januszewski,Kownacki,Smiglak,Maciejewski
, p. 59 - 63 (2018/02/09)
Functionalized siloxanes, as one of the most important classes of organosilicon compounds, are widely applied in industry. In our studies, we have investigated, the reaction between 1,1,3,3-tetramethyldisiloxane (TMDSO) and 1-octene, using the rhodium cat
Hydrosilylation of alkenes catalyzed by rhodium with polyethylene glycol-based ionic liquids as ligands
Xu, Yisong,Bai, Ying,Peng, Jiajian,Li, Jiayun,Xiao, Wenjun,Lai, Guoqiao
, p. 59 - 63 (2014/06/09)
A series of polyethylene glycol-functionalized imidazolium ionic liquids has been prepared and characterized. These ionic liquids have been successfully applied in the hydrosilylation of alkenes catalyzed by rhodium complexes. The effects of the length of the polyether chain, the amount of ionic liquid, and the reaction temperature on the catalytic performance of hydrosilylation have been investigated. Furthermore, the catalytic system has been tested for the hydrosilylation of different alkenes with triethoxysilane. The new catalytic system exhibits both excellent catalytic activity and selectivity under low-temperature conditions. The catalyst system could be recycled five times with slightly deactivation.