186487-68-3

Upstream product

• 4292-19-7 1-Iodododecane 
• 143-15-7 1-dodecylbromide 
• 540-37-4 p-aminoiodobenzene 
• 1066-54-2 trimethylsilylacetylene 
• 164264-73-7 4-(N,N-didodecylamino)benzaldehyde 
• 558-13-4 carbon tetrabromide 
• 186488-48-2 N,N-didodecyl-4-iodobenzenamine 
• 186489-04-3 4-[(trimethylsilyl)ethynyl]-(N,N-didodecylamino)benzene 

Downstream Products

• 186488-20-0 1-[4-(didodecylamino)phenyl]-3-{[4-(didodecylamino)phenyl]ethynyl}-4-[(triisopropylsilyl)ethynyl]-6-(trimethylsilyl)hex-3-ene-1,5-diyne 
• 686721-54-0 N,N-didodecyl-4-[4-(ethynyl)phenylethynyl]aniline 
• 686721-68-6 4-{4-[4-(didodecylamino)phenylethynyl]phenylethynyl}benzaldehyde 
• 686721-56-2 N,N-didodecyl-4-{4-[4-(ethynyl)phenylethynyl]phenylethynyl}aniline 
• 686721-55-1 N,N-didodecyl-4-{4-[4-(trimethylsilylethynyl)phenylethynyl]phenylethynyl}aniline 
• 686721-69-7 4-(4-{4-[4-(didodecylamino)phenylethynyl]phenylethynyl}phenylethynyl)benzaldehyde 
• 686721-57-3 N,N-didodecyl-4-(4-{4-[4-(trimethylsilylethynyl)phenylethynyl]phenylethynyl}phenylethynyl)aniline 
• 1631160-88-7 5-{4-[2-(4-didodecylaminophenyl)ethynyl]phenyl}-2H-tetrazole 
• 1453792-08-9 C₉₂H₁₄₄N₂O₂Si₂ 
• 1453792-07-8 C₉₂H₁₄₄N₂O₂Si₂ 
• 1453792-12-5 C₈₀H₁₁₄N₂O₂ 

Relevant academic research and scientific papers

Application of Near-IR Absorption Porphyrin Dyes Derived from Click Chemistry as Third-Order Nonlinear Optical Materials

Recently, third-order nonlinear properties of porphyrins and porphyrin polymers and coordination compounds have been extensively studied in relation to their use in photomedicine and molecular photonics. A new functionalized porphyrin dye containing elect

Dye sensitizer molecule taking triazole as core and preparation method of dye sensitizer molecule

The invention discloses a dye sensitizer molecule taking triazole as a core and a preparation method of the dye sensitizer molecule. According to the dye molecule, a triazole ring is introduced to the design of a molecular structure, and the electronic ab

Arylethynyl-substituted tristriazolotriazines: Synthesis, optical properties, and thermotropic behavior

The synthesis of C3-symmetrical tristriazolotriazines with conjugated arms and lateral alkoxy side chains was performed by a threefold condensation of cyanuric chloride with tetrazoles. Conjugated π segments include phenyl, tolane, and its phenylethynyl-elongated homologue. Disclike and a dendritic molecule have been obtained, and two compounds with a 3,4,5-tris(octyloxy) substitution form broad thermotropic mesophases. The linear optical properties, solvatochromism of the fluorescence, acidochromism, and the two-photon absorption efficiency of selected compounds are reported. Copyright

Efficient modification of pyrene-derivative featuring third-order nonlinear optics via the click post-functionalization

A series of pyrene derivatives featuring nonplanar structures of N,N-didodecylanilino-substituted donor and TCNE/TCNQ adduct acceptors have been efficiently synthesized via formal [2+2] cycloaddition. As the efficient click by TCNE and TCNQ, the products show strong charge-transfer (CT) bands in the visible (near-IR region), potent redox activities, and related photophysical properties. UV/vis spectra and electrochemical studies show that the CT properties of these systems are readily tunable by strong cyano acceptor introduction on the nucleophile, which have a larger effect on the lowest unoccupied molecular orbital (LUMO). In particular, compared with the adduct of TCNE, the product clicked with TCNQ possessed a stronger D-A conjugation and bulkier π spacers. The TCNQ product also has a larger third-order nonlinear optical property which was characterized by Z-scan experiments. This could point to potentially interesting applications of the new pyrene derivatives in optoelectronic devices and develop the new modification process for the design of different pyrene-based molecular electronic devices.

Red- and blue-shifts in oligo(1,4-phenyleneethynylene)s having terminal donor-acceptor substitutions

Four series of oligo(1,4-phenyleneethynylene)s (OPEs), 1-4 (a-d), each having a terminal dialkylamino group as their electron donor, were prepared by applying Sonogashira-Hagihara reactions and a protecting group strategy. To study the influence that the

Novel extended tetrathiafulvalenes based on acetylenic spacers: Synthesis and electronic properties

A selection of mono- and diacetylenic dithiafulvalenes was synthesized and employed for the construction of extended tetrathiafulvalenes (TTFs) with hexa-2,4-diyne-1,6-diylidene or deca-2,4,6,8-tetrayne-1,10-diylidene spacers between the two 1,3-dithiole

186. Donor/acceptor-substituted tetraethynylethenes: Systematic assembly of molecules for use as advanced materials

A comprehensive series of tetraethynylethenes (= 3,4-diethynylhex-3-ene-1,5-diynes, TEEs) bearing electron-donating (p-methoxyphenyl or p-aminophenyl) and/or electron-accepting (p-nitrophenyl) groups was prepared via [Pd]-catalyzed Sonogashira cross-coupl