186489-04-3

Upstream product

• 186488-48-2 N,N-didodecyl-4-iodobenzenamine 
• 1066-54-2 trimethylsilylacetylene 
• 4292-19-7 1-Iodododecane 
• 540-37-4 p-aminoiodobenzene 

Downstream Products

• 186487-80-9 1-[4-(didodecylamino)phenyl]-3-{[4-(didodecylamino)phenyl]ethynyl}-6-(triisopropylsilyl)-4-[(triisopropylsilyl)ethynyl]hex-3-ene-1,5-diyne 
• 186488-20-0 1-[4-(didodecylamino)phenyl]-3-{[4-(didodecylamino)phenyl]ethynyl}-4-[(triisopropylsilyl)ethynyl]-6-(trimethylsilyl)hex-3-ene-1,5-diyne 
• 396721-09-8 5-[4,5-bis(methoxycarbonyl)-1,3-dithiol-2-ylidene]-1-[4-(N,N-didodecylamino)phenyl]-7-(triisopropylsilyl)hepta-1,3,6-triyne 
• 686721-57-3 N,N-didodecyl-4-(4-{4-[4-(trimethylsilylethynyl)phenylethynyl]phenylethynyl}phenylethynyl)aniline 
• 686721-69-7 4-(4-{4-[4-(didodecylamino)phenylethynyl]phenylethynyl}phenylethynyl)benzaldehyde 
• 686721-55-1 N,N-didodecyl-4-{4-[4-(trimethylsilylethynyl)phenylethynyl]phenylethynyl}aniline 
• 686721-56-2 N,N-didodecyl-4-{4-[4-(ethynyl)phenylethynyl]phenylethynyl}aniline 
• 686721-68-6 4-{4-[4-(didodecylamino)phenylethynyl]phenylethynyl}benzaldehyde 
• 686721-53-9 N,N-didodecyl-4-[4-(trimethylsilylethynyl)phenylethynyl]aniline 
• 686721-54-0 N,N-didodecyl-4-[4-(ethynyl)phenylethynyl]aniline 
• 686721-67-5 4-[4-(didodecylamino)phenylethynyl]benzaldehyde 

Relevant academic research and scientific papers

Application of Near-IR Absorption Porphyrin Dyes Derived from Click Chemistry as Third-Order Nonlinear Optical Materials

Recently, third-order nonlinear properties of porphyrins and porphyrin polymers and coordination compounds have been extensively studied in relation to their use in photomedicine and molecular photonics. A new functionalized porphyrin dye containing elect

Efficient modification of pyrene-derivative featuring third-order nonlinear optics via the click post-functionalization

A series of pyrene derivatives featuring nonplanar structures of N,N-didodecylanilino-substituted donor and TCNE/TCNQ adduct acceptors have been efficiently synthesized via formal [2+2] cycloaddition. As the efficient click by TCNE and TCNQ, the products show strong charge-transfer (CT) bands in the visible (near-IR region), potent redox activities, and related photophysical properties. UV/vis spectra and electrochemical studies show that the CT properties of these systems are readily tunable by strong cyano acceptor introduction on the nucleophile, which have a larger effect on the lowest unoccupied molecular orbital (LUMO). In particular, compared with the adduct of TCNE, the product clicked with TCNQ possessed a stronger D-A conjugation and bulkier π spacers. The TCNQ product also has a larger third-order nonlinear optical property which was characterized by Z-scan experiments. This could point to potentially interesting applications of the new pyrene derivatives in optoelectronic devices and develop the new modification process for the design of different pyrene-based molecular electronic devices.

Red- and blue-shifts in oligo(1,4-phenyleneethynylene)s having terminal donor-acceptor substitutions

Four series of oligo(1,4-phenyleneethynylene)s (OPEs), 1-4 (a-d), each having a terminal dialkylamino group as their electron donor, were prepared by applying Sonogashira-Hagihara reactions and a protecting group strategy. To study the influence that the

186. Donor/acceptor-substituted tetraethynylethenes: Systematic assembly of molecules for use as advanced materials

A comprehensive series of tetraethynylethenes (= 3,4-diethynylhex-3-ene-1,5-diynes, TEEs) bearing electron-donating (p-methoxyphenyl or p-aminophenyl) and/or electron-accepting (p-nitrophenyl) groups was prepared via [Pd]-catalyzed Sonogashira cross-coupl