1865-45-8

Upstream product

• 62-53-3 aniline 
• 497-19-8 sodium carbonate 
• 7440-23-5 sodium 
• 108-91-8 cyclohexylamine 
• 98-95-3 nitrobenzene 
• 1227476-15-4 Azobenzene 

Downstream Products

• 5468-85-9 N-phenylquinolin-2-amine 
• 271-34-1 5-azaindole 
• 116-90-5 4,4'-dibenzanthronyl 
• 52776-50-8 4-anilino-benz[de]anthracen-7-one 
• 5521-31-3 N,N'-Dimethylperylene-3,4,9,10-biscarboximide 
• 100-61-8 N-methylaniline 
• 3056-73-3 N-phenylcinnamamide 
• 58655-60-0 diethyl-malonic acid-dianilide 
• 1611-83-2 2-methyl-N-phenylacrylamide 
• 128-64-3 isoviolanthrone 
• 116-71-2 isoviolanthrone 
• 3920-79-4 N-phenyl-N-(9-phenanthryl)amine 
• 34087-01-9 5-phenyl-5,14-dihydro-naphtho[2,3-a]phenazine-8,13-dione 
• 1749-19-5 phenyl(1-phenylethylidene)amine 

Relevant academic research and scientific papers

Preparation method and application of amino metal compound

The invention discloses a preparation method of an amino metal compound. The method comprises the following steps: contacting an amino compound with a metal source, and reacting the amino compound with the metal source to obtain the amino metal compound.

Amino metal compound and preparation and application thereof

The invention discloses an amino metal compound as well as preparation and application thereof. The amino metal compound is aniline sodium or sodium cyclohexylamine, and the chemical formula of the amino metal compound is C6H6NNa or C6H12NNa. The preparation method comprises a ball milling method or a solution method, and has the advantages that the method is simple and easy to implement, the reaction is thorough, the reaction degree can be monitored, the reaction is easy to amplify and the like. As hydrogen storage materials, sodium aniline and sodium cyclohexylamine prepared by the method have the advantages of high hydrogen storage capacity, low cost, mild hydrogen storage operation temperature and the like.

Sodium anilinide-cyclohexylamide pair: Synthesis, characterization, and hydrogen storage properties

The lack of efficient hydrogen storage material is one of the bottlenecks for the large-scale implementation of hydrogen energy. Here, a series of new hydrogen storage materials, i.e., anilinide-cyclohexylamide pairs, are proposed via the metallation of an aniline-cyclohexylamine pair. DFT calculations show that the enthalpy change of hydrogen desorption (ΔHd) can be significantly tuned from 60.0 kJ per mol-H2 for the pristine aniline-cyclohexylamine pair to 42.2 kJ per mol-H2 for sodium anilinide-cyclohexylamide and 38.7 kJ per mol-H2 for potassium anilinide-cyclohexylamide, where an interesting correlation between the electronegativity of the metal and the ΔHd was observed. Experimentally, the sodium anilinide-cyclohexylamide pair was successfully synthesised with a theoretical hydrogen capacity of 4.9 wt%, and the hydrogenation and dehydrogenation cycle can be achieved at a relatively low temperature of 150 °C in the presence of commercial catalysts, in clear contrast to the pristine aniline-cyclohexylamine pair which undergoes dehydrogenation at elevated temperatures.